70YbYtterbium

Ytterbium is a chemical element with the symbol Yb and atomic number 70. It is a metal, the fourteenth and penultimate element in the lanthanide series, which is the basis of the relative stability of its +2 oxidation state. Like the other lanthanides, its most common oxidation state is +3, as in its oxide, halides, and other compounds. In aqueous solution, like compounds of other late lanthanides, soluble ytterbium compounds form complexes with nine water molecules. Because of its closed-shell electron configuration, its density and melting and boiling points differ significantly from those of most other lanthanides.

In 1878, Swiss chemist Jean Charles Galissard de Marignac separated from the rare earth "erbia" (another independent component) which he called "ytterbia", for Ytterby, the village in Sweden near where he found the new component of erbium. He suspected that ytterbia was a compound of a new element that he called "ytterbium" (in total, four elements were named after the village, the others being yttrium, terbium, and erbium). In 1907, the new earth "lutecia" was separated from ytterbia, from which the element "lutecium" (now lutetium) was extracted by Georges Urbain, Carl Auer von Welsbach, and Charles James. After some discussion, Marignac's name "ytterbium" was retained. A relatively pure sample of the metal was not obtained until 1953. At present, ytterbium is mainly used as a dopant of stainless steel or active laser media, and less often as a gamma ray source.

Natural ytterbium is a mixture of seven stable isotopes, which altogether are present at concentrations of 0. 3 parts per million. This element is mined in China, the United States, Brazil, and India in form of the minerals monazite, euxenite, and xenotime. The ytterbium concentration is low because it is found only among many other rare-earth elements; moreover, it is among the least abundant. Once extracted and prepared, ytterbium is somewhat hazardous as an eye and skin irritant. The metal is a fire and explosion hazard.

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Atomic properties

Standard atomic weight173.045 ±0.01
Atomic mass173.045 u

Atomic radii

Radius (empirical)176 pm
Radius (calculated)222 pm
Covalent radius187 ±8 pm

Atomic shell

Electron configurationXe 4f14 6s2
Ionization energy(1st) 6.25416 eV
(2nd) 12.179185 eV
(3rd) 25.053 eV
(4th) 43.61 eV
(5th) 65.6 eV
Shell model
Electrons
k-shell:2
l-shell:8
m-shell:18
n-shell:32
o-shell:8
p-shell:2

Physical properties

Phasesolid
Density6.973 g·cm−3 (298.1 K)
Molar volume2.484·10-5 m3·mol−1
Speed of sound1,590 m·s−1 (293.1 K)

Temperatures

Melting point1,097 K
Boiling point1,469 K
Liquid range372 K

Enthalpies

Melting enthalpy7.7 kJ·mol-1
Enthalpy of vaporization160 kJ·mol-1
Binding energy152 kJ·mol-1

Heat and conductivity

Thermal conductivity39 W·m-1·K-1
Expansion coefficient2.63·10-5 K-1

Hardnesses

Brinell hardness343 NM·m-2
Vickers hardness206 NM·m-2

Elastic properties

Young’s modulus24 GPa
Shear modulus9.9 GPa
Bulk modulus31 GPa
Poisson’s ratio0.21

Electrical properties

Electrical conductivity4·106 S·m-1
Resistance2.5·10-7 Ωm

Magnetism

Magnetismparamagnetic
Magnetic susceptibility2.49·10-4 cm3·mol−1 (298 K)

Chemical properties

Basicityslightly basic
Oxidation state2, 3
Standard potential-2.22 V (Yb3+ + 3e- → Yb)

Electronegativity

Allred-Rochow scale1.06
Nagle scale1.13

Other properties

Natural occurrenceprimordial
Crystal structureFace-centered cubic
Goldschmidt Classificationlithophile
Superconductorwithout transition tempperature
Price/kg17.1 USD

Natural abundances

satellite_alt
Universe
2 ppb ≈ 2.01·1010 M☉
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Sun
1 ppb ≈ 1.98·109 Mt
destruction
Meteorite
180 ppb ≈ 180 mg
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Earth’s crust
2,800 ppb ≈ 77,500 Mt
water_drop
Oceans
8·10-4 ppb ≈ 1.09 kt
waves
Flowing water
0.05 ppb ≈ 800 t
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