1HHydrogen

Hydrogen is a chemical element; it has the symbol H and atomic number 1. It is the lightest and most abundant chemical element in the universe, constituting about 75% of all normal matter. Under standard conditions, hydrogen is a gas of diatomic molecules with the formula H2, called dihydrogen, or sometimes hydrogen gas, molecular hydrogen, or simply hydrogen. Dihydrogen is colorless, odorless, non-toxic, and highly combustible. Stars, including the Sun, mainly consist of hydrogen in a plasma state, while on Earth, hydrogen is found as the gas H2 (dihydrogen) and in molecules, such as in water and organic compounds. The most common isotope of hydrogen, 1H, consists of one proton, one electron, and no neutrons.

Hydrogen gas was first produced artificially in the 17th century by the reaction of acids with metals. Henry Cavendish, in 1766–1781, identified hydrogen gas as a distinct substance and discovered its property of producing water when burned: this is the origin of hydrogen's name, which means 'water-former' (from Ancient Greek: ὕδωρ, romanized: húdōr, lit. 'water', and γεννάω, gennáō, 'I bring forth'). Understanding the colors of light absorbed and emitted by hydrogen was a crucial part of the development of quantum mechanics.

Hydrogen, typically nonmetallic except under extreme pressure, readily forms covalent bonds with most nonmetals, contributing to the formation of compounds like water and various organic substances. Its role is crucial in acid-base reactions, which mainly involve proton exchange among soluble molecules. In ionic compounds, hydrogen can take the form of either a negatively-charged anion, where it is known as hydride, or as a positively-charged cation, H+, called a proton. Although tightly bonded to water molecules, protons strongly affect the behavior of aqueous solutions, as reflected in the importance of pH. Hydride, on the other hand, is rarely observed because it tends to deprotonate solvents, yielding H2.

In the early universe, neutral hydrogen atoms formed about 370,000 years after the Big Bang as the universe expanded and plasma had cooled enough for electrons to remain bound to protons. After stars began to form, most of the hydrogen in the intergalactic medium was re-ionized.

Nearly all hydrogen production is done by transforming fossil fuels, particularly steam reforming of natural gas. It can also be produced from water or saline by electrolysis, but this process is more expensive. Its main industrial uses include fossil fuel processing and ammonia production for fertilizer. Emerging uses for hydrogen include the use of fuel cells to generate electricity.

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Atomic properties

Standard atomic weight1.008 ±2·10-4 [1.00784 … 1.00811]
Atomic mass1.0081 u

Atomic radii

Radius (empirical)25 pm
Radius (calculated)53 pm
Covalent radius31 ±5 pm
Van der Waals radius120 pm

Atomic shell

Electron configuration1s1
Ionization energy(1st) 13.598434 eV
Shell model
Electrons
k-shell:1

Physical properties

Phasegaseous
Densitygaseous: 0.0899 kg·m−3 (273 K)
liquid: 0.0709 kg·l−1 (20.32 K)
Molar volumesolid: 1.142·10-5 m3·mol−1
Speed of sound1,270 m·s−1 (298.1 K)

Temperatures

Melting point13.99 K
Boiling point20.27 K
Liquid range6.281 K
Triple point13.8 K @ 7.041 kPa
Critical point32.93 K @ 1.285 MPa

Enthalpies

Melting enthalpy0.558 kJ·mol-1
Enthalpy of vaporization0.452 kJ·mol-1
Binding energy218 kJ·mol-1

Heat and conductivity

Specific heat capacity14,300 J·kg−1·K−1
Thermal conductivity0.1805 W·m-1·K-1

Magnetism

Magnetismdiamagnetic
Magnetic susceptibility-3.98·10-6 cm3·mol−1 (298 K)

Optical properties

Refractive indexgaseous: 1
liquid: 1.12

Chemical properties

Basicityamphoteric
Oxidation state+1, 0, -1
Standard potential0 V

Electronegativity

Pauling scale2.2
Sanderson scale2.59
Allred-Rochow scale2.2
Mulliken scale2.25
Allen scale2.3
Ghosh-Gupta scale7.186 eV
Nagle scale2.27
Pearson absolute negativity7.18 eV

Other properties

Natural occurrenceprimordial
Crystal structureHexagonal
Goldschmidt Classificationatmophile
Superconductorwithout transition temperature
Price/kg1.39 USD

Natural abundances

satellite_alt
Universe
7.5·108 ppb ≈ 7.54·1018 M☉
sunny
Sun
7.5·108 ppb ≈ 1.49·1018 Mt
destruction
Meteorite
2.4·107 ppb ≈ 24 kg
public
Earth’s crust
1.5·106 ppb ≈ 4.15·107 Mt
water_drop
Oceans
1.078·108 ppb ≈ 147,000 Mt
waves
Flowing water
1.15·108 ppb ≈ 1,840 Mt
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Human body
1·108 ppb ≈ 7 kg