38SrStrontium

Strontium is the chemical element with the symbol Sr and atomic number 38. An alkaline earth metal, strontium is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is exposed to air. Strontium has physical and chemical properties similar to those of its two vertical neighbors in the periodic table, calcium and barium. It occurs naturally mainly in the minerals celestine and strontianite, and is mostly mined from these.

Both strontium and strontianite are named after Strontian, a village in Scotland near which the mineral was discovered in 1790 by Adair Crawford and William Cruickshank; it was identified as a new element the next year from its crimson-red flame test color. Strontium was first isolated as a metal in 1808 by Humphry Davy using the then newly discovered process of electrolysis. During the 19th century, strontium was mostly used in the production of sugar from sugar beets (see strontian process). At the peak of production of television cathode-ray tubes, as much as 75% of strontium consumption in the United States was used for the faceplate glass. With the replacement of cathode-ray tubes with other display methods, consumption of strontium has dramatically declined. While natural strontium (which is mostly the isotope strontium-88) is stable, the synthetic strontium-90 is radioactive and is one of the most dangerous components of nuclear fallout, as strontium is absorbed by the body in a similar manner to calcium. Natural stable strontium, on the other hand, is not hazardous to health.

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Atomic properties

Standard atomic weight87.62 ±0.01
Atomic mass87.621 u

Atomic radii

Radius (empirical)215 pm
Radius (calculated)219 pm
Covalent radius195 ±10 pm
Van der Waals radius249 pm

Atomic shell

Electron configurationKr 5s2
Ionization energy(1st) 5.6948674 eV
(2nd) 11.030276 eV
(3rd) 42.88353 eV
(4th) 56.28 eV
(5th) 70.7 eV
Shell model
Electrons
k-shell:2
l-shell:8
m-shell:18
n-shell:8
o-shell:2

Physical properties

Phasesolid
Density2.63 g·cm−3 (293.1 K)
Molar volume3.394·10-5 m3·mol−1

Temperatures

Melting point1,050 K
Boiling point1,650 K
Liquid range600 K
Transition temperature4 K

Enthalpies

Melting enthalpy8 kJ·mol-1
Enthalpy of vaporization137 kJ·mol-1
Binding energy164 kJ·mol-1

Heat and conductivity

Thermal conductivity35 W·m-1·K-1
Expansion coefficient2.25·10-5 K-1
Work function2.59 eV

Hardnesses

Mohs hardness1.5

Elastic properties

Shear modulus6.1 GPa
Poisson’s ratio0.28

Electrical properties

Electrical conductivity7.41·106 S·m-1
Resistance1.35·10-7 Ωm

Magnetism

Magnetismparamagnetic
Magnetic susceptibility-9.201·10-5 cm3·mol−1 (298 K)

Chemical properties

Basicitystrongly basic
Oxidation state+2
Standard potential-2.89 V (Sr2+ + 2e- → Sr)

Electronegativity

Pauling scale0.95
Sanderson scale0.72
Allred-Rochow scale0.99
Mulliken scale1
Allen scale0.963
Ghosh-Gupta scale2.584 eV
Nagle scale1.06
Pearson absolute negativity2 eV

Other properties

Natural occurrenceprimordial
Crystal structureFace-centered cubic
Goldschmidt Classificationlithophile
Superconductorwith transition tempperature under special conditions
Price/kg6.61 ±0.08 USD

Natural abundances

satellite_alt
Universe
40 ppb ≈ 4.02·1011 M☉
sunny
Sun
50 ppb ≈ 9.94·1010 Mt
destruction
Meteorite
8,900 ppb ≈ 8.9 g
public
Earth’s crust
360,000 ppb ≈ 9.97·106 Mt
water_drop
Oceans
8,100 ppb ≈ 11 Mt
waves
Flowing water
60 ppb ≈ 959 kt
accessibility_new
Human body
4,600 ppb ≈ 322 mg