82PbLead

Lead ( ) is a chemical element with the symbol Pb (from the Latin plumbum) and atomic number 82. It is a heavy metal, denser than most common materials. Lead is soft, malleable, and has a relatively low melting point. When freshly cut, it appears shiny gray with a bluish tint, but tarnishes to dull gray on exposure to air. Lead has the highest atomic number of any stable element, and three of its isotopes are endpoints of major nuclear decay chains of heavier elements.

Lead is a relatively unreactive post-transition metal. Its weak metallic character is shown by its amphoteric behavior: lead and lead oxides react with both acids and bases, and it tends to form covalent bonds. Lead compounds usually occur in the +2 oxidation state rather than the +4 state common in lighter members of the carbon group, with exceptions mostly limited to organolead compounds. Like the lighter members of the group, lead can bond with itself, forming chains and polyhedral structures.

Easily extracted from its ores, lead was known to prehistoric peoples in the Near East. Galena is its principal ore and often contains silver, encouraging its widespread extraction and use in ancient Rome. Production declined after the fall of Rome and did not reach similar levels until the Industrial Revolution. Lead played a role in developing the printing press, as movable type could be readily cast from lead alloys. In 2014, annual global production was about ten million tonnes, over half from recycling. Lead's high density, low melting point, ductility, and resistance to oxidation, together with its abundance and low cost, supported its extensive use in construction, plumbing, batteries, ammunition, weights, solders, pewter, fusible alloys, lead paints, leaded gasoline, and radiation shielding.

Lead is a neurotoxin that accumulates in soft tissues and bones. It damages the nervous system, interferes with biological enzymes, and can cause neurological disorders ranging from behavioral problems to brain damage. It also affects cardiovascular and renal systems. Lead's toxicity was noted by ancient Greek and Roman writers, but became widely recognized in Europe in the late 19th century.

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Atomic properties

Standard atomic weight207.2 ±1.1 [206.14 … 207.94]
Atomic mass207.21 u

Atomic radii

Radius (empirical)175 pm
Radius (calculated)154 pm
Covalent radius146 ±5 pm
Van der Waals radius202 pm

Atomic shell

Electron configurationXe 4f14 5d10 6s2 6p2
Ionization energy(1st) 7.4166799 eV
(2nd) 15.032499 eV
(3rd) 31.9373 eV
(4th) 42.33256 eV
(5th) 68.8 eV
Shell model
Electrons
k-shell:2
l-shell:8
m-shell:18
n-shell:32
o-shell:18
p-shell:4

Physical properties

Phasesolid
Density11.34 g·cm−3 (293.1 K)
Molar volume1.826·10-5 m3·mol−1
Speed of sound1,260 m·s−1 (293.1 K)

Temperatures

Melting point600.6 K
Boiling point2,022 K
Liquid range1,421 K
Transition temperature7.2 K

Enthalpies

Melting enthalpy4.77 kJ·mol-1
Enthalpy of vaporization178 kJ·mol-1
Binding energy195 kJ·mol-1

Heat and conductivity

Specific heat capacity131 J·kg−1·K−1
Thermal conductivity35 W·m-1·K-1
Expansion coefficient2.89·10-5 K-1

Hardnesses

Mohs hardness1.5
Brinell hardness38.3 NM·m-2

Elastic properties

Young’s modulus16 GPa
Shear modulus5.6 GPa
Bulk modulus46 GPa
Poisson’s ratio0.44

Electrical properties

Electrical conductivity4.76·106 S·m-1
Resistance2.1·10-7 Ωm

Magnetism

Magnetismdiamagnetic
Magnetic susceptibility-2.301·10-5 cm3·mol−1 (298 K)

Chemical properties

Basicityamphoteric
Oxidation state2, 4
Standard potential-0.1251 V (Pb2+ + 2e- → Pb)

Electronegativity

Pauling scale2.33
Sanderson scale2.29
Allred-Rochow scale1.55
Mulliken scale2.41
Nagle scale1.76
Pearson absolute negativity3.9 eV

Other properties

Natural occurrenceprimordial
Crystal structureFace-centered cubic
Goldschmidt Classificationchalcophile
Superconductorwith transition temperature (solid body, normal pressure)
Price/kg2 USD

Natural abundances

satellite_alt
Universe
10 ppb ≈ 1·1011 M☉
sunny
Sun
10 ppb ≈ 1.98·1010 Mt
destruction
Meteorite
1,400 ppb ≈ 1.4 g
public
Earth’s crust
10,000 ppb ≈ 277,000 Mt
water_drop
Oceans
0.03 ppb ≈ 41.1 kt
waves
Flowing water
3 ppb ≈ 48 kt
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Human body
1,700 ppb ≈ 119 mg