48CdCadmium

Cadmium is a chemical element with the symbol Cd and atomic number 48. This soft, silvery-white metal is chemically similar to the two other stable metals in group 12, zinc and mercury. Like zinc, it demonstrates oxidation state +2 in most of its compounds, and like mercury, it has a lower melting point than the transition metals in groups 3 through 11. Cadmium and its congeners in group 12 are often not considered transition metals, in that they do not have partly filled d or f electron shells in the elemental or common oxidation states. The average concentration of cadmium in Earth's crust is between 0. 1 and 0. 5 parts per million (ppm). It was discovered in 1817 simultaneously by Stromeyer and Hermann, both in Germany, as an impurity in zinc carbonate.

Cadmium occurs as a minor component in most zinc ores and is a byproduct of zinc production. Cadmium was used for a long time as a corrosion-resistant plating on steel, and cadmium compounds are used as red, orange, and yellow pigments, to color glass, and to stabilize plastic. Cadmium use is generally decreasing because it is toxic (it is specifically listed in the European Restriction of Hazardous Substances Directive) and nickel–cadmium batteries have been replaced with nickel–metal hydride and lithium-ion batteries. One of its few new uses is in cadmium telluride solar panels.

Although cadmium has no known biological function in higher organisms, a cadmium-dependent carbonic anhydrase has been found in marine diatoms.

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Atomic properties

Standard atomic weight112.414 ±0.004
Atomic mass112.414 u

Atomic radii

Radius (empirical)151 pm
Radius (calculated)161 pm
Covalent radius144 ±9 pm
Van der Waals radius158 pm

Atomic shell

Electron configurationKr 4d10 5s2
Ionization energy(1st) 8.99382 eV
(2nd) 16.908313 eV
(3rd) 37.468 eV
(4th) 51 eV
(5th) 67.9 eV
Shell model
Electrons
k-shell:2
l-shell:8
m-shell:18
n-shell:18
o-shell:2

Physical properties

Phasesolid
Density8.65 g·cm−3 (298.1 K)
Molar volume1.3·10-5 m3·mol−1
Speed of sound2,310 m·s−1 (293.1 K)

Temperatures

Melting point594.2 K
Boiling point1,040 K
Liquid range445.7 K
Transition temperature0.52 K

Enthalpies

Melting enthalpy6.3 kJ·mol-1
Enthalpy of vaporization100 kJ·mol-1
Binding energy112 kJ·mol-1

Heat and conductivity

Thermal conductivity97 W·m-1·K-1
Expansion coefficient3.08·10-5 K-1
Work function4.2 eV

Hardnesses

Mohs hardness2
Brinell hardness203 NM·m-2

Elastic properties

Young’s modulus50 GPa
Shear modulus19 GPa
Bulk modulus42 GPa
Poisson’s ratio0.3

Electrical properties

Electrical conductivity1.43·107 S·m-1
Resistance7·10-8 Ωm

Magnetism

Magnetismdiamagnetic
Magnetic susceptibility-1.981·10-5 cm3·mol−1

Optical properties

Reflectivity67 %

Chemical properties

Basicityslightly basic
Oxidation state2
Standard potential-0.403 V (Cd2+ + 2e- → Cd)

Electronegativity

Pauling scale1.69
Sanderson scale1.98
Allred-Rochow scale1.46
Mulliken scale1.53
Ghosh-Gupta scale3.795 eV
Nagle scale1.45
Pearson absolute negativity4.33 eV

Other properties

Natural occurrenceprimordial
Crystal structureHexagonal close-packed
Goldschmidt Classificationchalcophile
Superconductorwith transition tempperature (solid body, normal pressure)
Price/kg2.73 USD

Natural abundances

satellite_alt
Universe
2 ppb ≈ 2.01·1010 M☉
sunny
Sun
6 ppb ≈ 1.19·1010 Mt
destruction
Meteorite
450 ppb ≈ 450 mg
public
Earth’s crust
150 ppb ≈ 4,150 Mt
water_drop
Oceans
0.05 ppb ≈ 68.5 kt
waves
Flowing water
700 ppb ≈ 11.2 Gt
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