47AgSilver

Silver is a chemical element with the symbol Ag (from Latin argentum 'silver', derived from the Proto-Indo-European h₂erǵ 'shiny, white') and atomic number 47. A soft, white, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. The metal is found in the Earth's crust in the pure, free elemental form ("native silver"), as an alloy with gold and other metals, and in minerals such as argentite and chlorargyrite. Most silver is produced as a byproduct of copper, gold, lead, and zinc refining.

Silver has long been valued as a precious metal. Silver metal is used in many bullion coins, sometimes alongside gold: while it is more abundant than gold, it is much less abundant as a native metal. Its purity is typically measured on a per-mille basis; a 94%-pure alloy is described as "0. 940 fine". As one of the seven metals of antiquity, silver has had an enduring role in most human cultures.

Other than in currency and as an investment medium (coins and bullion), silver is used in solar panels, water filtration, jewellery, ornaments, high-value tableware and utensils (hence the term "silverware"), in electrical contacts and conductors, in specialized mirrors, window coatings, in catalysis of chemical reactions, as a colorant in stained glass, and in specialized confectionery. Its compounds are used in photographic and X-ray film. Dilute solutions of silver nitrate and other silver compounds are used as disinfectants and microbiocides (oligodynamic effect), added to bandages, wound-dressings, catheters, and other medical instruments.

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Atomic properties

Standard atomic weight107.868 ±2·10-4
Atomic mass107.868 u

Atomic radii

Radius (empirical)144 pm
Radius (calculated)165 pm
Covalent radius145 ±5 pm
Van der Waals radius172 pm

Atomic shell

Electron configurationKr 4d10 5s1
Ionization energy(1st) 7.576234 eV
(2nd) 21.4844 eV
(3rd) 34.8 eV
(4th) 49 eV
(5th) 65 eV
Shell model
Electrons
k-shell:2
l-shell:8
m-shell:18
n-shell:18
o-shell:1

Physical properties

Phasesolid
Density10.49 g·cm−3 (293.1 K)
Molar volume1.027·10-5 m3·mol−1
Speed of sound2,600 m·s−1

Temperatures

Melting point1,234 K
Boiling point2,435 K
Liquid range1,200 K

Enthalpies

Melting enthalpy11.3 kJ·mol-1
Enthalpy of vaporization255 kJ·mol-1
Binding energy285 kJ·mol-1

Heat and conductivity

Specific heat capacity235 J·kg−1·K−1 (298.1 K)
Thermal conductivity430 W·m-1·K-1
Expansion coefficient1.89·10-5 K-1
Work function4.26 eV

Hardnesses

Mohs hardness2.53
Brinell hardness24.5 NM·m-2
Vickers hardness251 NM·m-2

Elastic properties

Young’s modulus83 GPa
Shear modulus30 GPa
Bulk modulus100 GPa
Poisson’s ratio0.37

Electrical properties

Electrical conductivity6.14·107 S·m-1
Resistance1.63·10-8 Ωm

Magnetism

Magnetismdiamagnetic
Magnetic susceptibility-1.951·10-5 cm3·mol−1 (296 K)

Optical properties

Reflectivity97 %

Chemical properties

Basicityamphoteric
Oxidation state+1, +2, +3
Standard potential0.7991 V (Ag+ + e- → Ag)

Electronegativity

Pauling scale1.93
Sanderson scale1.83
Allred-Rochow scale1.42
Mulliken scale1.47
Ghosh-Gupta scale3.684 eV
Nagle scale1.45
Pearson absolute negativity4.44 eV

Other properties

Natural occurrenceprimordial
Crystal structureFace-centered cubic
Goldschmidt Classificationchalcophile
Superconductorwithout transition tempperature
Price/kg521 USD

Natural abundances

satellite_alt
Universe
0.6 ppb ≈ 6.03·109 M☉
sunny
Sun
1 ppb ≈ 1.98·109 Mt
destruction
Meteorite
140 ppb ≈ 140 mg
public
Earth’s crust
80 ppb ≈ 2,210 Mt
water_drop
Oceans
0.1 ppb ≈ 137 kt
waves
Flowing water
0.3 ppb ≈ 4.8 kt
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