67HoHolmium

Holmium is a chemical element with the symbol Ho and atomic number 67. It is a rare-earth element and the eleventh member of the lanthanide series. It is a relatively soft, silvery, fairly corrosion-resistant and malleable metal. Like many other lanthanides, holmium is too reactive to be found in native form, as pure holmium slowly forms a yellowish oxide coating when exposed to air. When isolated, holmium is relatively stable in dry air at room temperature. However, it reacts with water and corrodes readily, and also burns in air when heated.

In nature, holmium occurs together with the other rare-earth metals (like thulium). It is a relatively rare lanthanide, making up 1. 4 parts per million of the Earth's crust, an abundance similar to tungsten. Holmium was discovered through isolation by Swedish chemist Per Theodor Cleve. It was also independently discovered by Jacques-Louis Soret and Marc Delafontaine, who together observed it spectroscopically in 1878. Its oxide was first isolated from rare-earth ores by Cleve in 1878. The element's name comes from Holmia, the Latin name for the city of Stockholm. Like many other lanthanides, holmium is found in the minerals monazite and gadolinite and is usually commercially extracted from monazite using ion-exchange techniques. Its compounds in nature and in nearly all of its laboratory chemistry are trivalently oxidized, containing Ho(III) ions. Trivalent holmium ions have fluorescent properties similar to many other rare-earth ions (while yielding their own set of unique emission light lines), and thus are used in the same way as some other rare earths in certain laser and glass-colorant applications.

Holmium has the highest magnetic permeability and magnetic saturation of any element and is thus used for the pole pieces of the strongest static magnets. Because holmium strongly absorbs neutrons, it is also used as a burnable poison in nuclear reactors.

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Atomic properties

Standard atomic weight164.93 ±5·10-6
Atomic mass164.93 u

Atomic radii

Radius (empirical)176 pm
Radius (calculated)226 pm
Covalent radius192 ±7 pm

Atomic shell

Electron configurationXe 4f11 6s2
Ionization energy(1st) 6.0215 eV
(2nd) 11.781 eV
(3rd) 22.79 eV
(4th) 42.52 eV
(5th) 63.9 eV
Shell model
Electrons
k-shell:2
l-shell:8
m-shell:18
n-shell:29
o-shell:8
p-shell:2

Physical properties

Phasesolid
Density8.78 g·cm−3 (298.1 K)
Molar volume1.874·10-5 m3·mol−1
Speed of sound2,760 m·s−1

Temperatures

Melting point1,734 K
Boiling point2,873 K
Liquid range1,139 K

Enthalpies

Melting enthalpy17 kJ·mol-1
Enthalpy of vaporization265 kJ·mol-1
Binding energy301 kJ·mol-1

Heat and conductivity

Thermal conductivity16 W·m-1·K-1
Expansion coefficient1.12·10-5 K-1

Hardnesses

Brinell hardness746 NM·m-2
Vickers hardness481 NM·m-2

Elastic properties

Young’s modulus65 GPa
Shear modulus26 GPa
Bulk modulus40 GPa
Poisson’s ratio0.23

Electrical properties

Electrical conductivity1.23·106 S·m-1
Resistance8.14·10-7 Ωm

Magnetism

Magnetismparamagnetic

Chemical properties

Basicityslightly basic
Oxidation state3
Standard potential-2.33 V (Ho3+ + 3e- → Ho)

Electronegativity

Pauling scale1.23
Allred-Rochow scale1.1
Nagle scale1.1

Other properties

Natural occurrenceprimordial
Crystal structureHexagonal close-packed
Goldschmidt Classificationlithophile
Superconductorwithout transition tempperature
Price/kg57.1 USD

Natural abundances

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Universe
0.5 ppb ≈ 5.02·109 M☉
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destruction
Meteorite
60 ppb ≈ 60 mg
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Earth’s crust
1,200 ppb ≈ 33,200 Mt
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Oceans
2.2·10-4 ppb ≈ 301 t
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Flowing water
0.01 ppb ≈ 160 t
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