Lutetium is a chemical element with the symbol Lu and atomic number 71. It is a silvery white metal, which resists corrosion in dry air, but not in moist air. Lutetium is the last element in the lanthanide series, and it is traditionally counted among the rare earth elements; it can also be classified as the first element of the 6th-period transition metals. Lutetium was independently discovered in 1907 by French scientist Georges Urbain, Austrian mineralogist Baron Carl Auer von Welsbach, and American chemist Charles James. All of these researchers found lutetium as an impurity in the mineral ytterbia, which was previously thought to consist entirely of ytterbium. The dispute on the priority of the discovery occurred shortly after, with Urbain and Welsbach accusing each other of publishing results influenced by the published research of the other; the naming honor went to Urbain, as he had published his results earlier. He chose the name lutecium for the new element, but in 1949 the spelling was changed to lutetium. In 1909, the priority was finally granted to Urbain and his names were adopted as official ones; however, the name cassiopeium (or later cassiopium) for element 71 proposed by Welsbach was used by many German scientists until the 1950s. Lutetium is not a particularly abundant element, although it is significantly more common than silver in the Earth's crust. It has few specific uses. Lutetium-176 is a relatively abundant (2. 5%) radioactive isotope with a half-life of about 38 billion years, used to determine the age of minerals and meteorites. Lutetium usually occurs in association with the element yttrium and is sometimes used in metal alloys and as a catalyst in various chemical reactions. 177Lu-DOTA-TATE is used for radionuclide therapy (see Nuclear medicine) on neuroendocrine tumours. Lutetium has the highest Brinell hardness of any lanthanide, at 890–1300 MPa.
71LuLutetium
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Atomic properties
Standard atomic weight | 174.966 ±1·10-4 |
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Atomic mass | 174.966 u |
Atomic radii
Radius (empirical) | 174 pm |
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Radius (calculated) | 217 pm |
Covalent radius | 187 ±8 pm |
Atomic shell
Electron configuration | Xe 4f14 5d1 6s2 |
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Ionization energy | (1st) 5.425871 eV (2nd) 14.13 eV (3rd) 20.9594 eV (4th) 45.249 eV (5th) 66.8 eV |
Shell model | Electrons k-shell:2 l-shell:8 m-shell:18 n-shell:32 o-shell:9 p-shell:2 |
Physical properties
Phase | solid |
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Density | 9.84 g·cm−3 (298.1 K) |
Molar volume | 1.778·10-5 m3·mol−1 |
Temperatures
Melting point | 1,925 K |
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Boiling point | 3,675 K |
Liquid range | 1,750 K |
Transition temperature | 0.1 K |
Enthalpies
Melting enthalpy | (22 kJ·mol-1) |
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Enthalpy of vaporization | 415 kJ·mol-1 |
Binding energy | 428 kJ·mol-1 |
Heat and conductivity
Thermal conductivity | 16 W·m-1·K-1 |
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Expansion coefficient | 9.9·10-6 K-1 |
Hardnesses
Brinell hardness | 893 NM·m-2 |
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Vickers hardness | 1,160 NM·m-2 |
Elastic properties
Young’s modulus | 69 GPa |
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Shear modulus | 27 GPa |
Bulk modulus | 48 GPa |
Poisson’s ratio | 0.26 |
Electrical properties
Electrical conductivity | 1.72·106 S·m-1 |
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Resistance | 5.8·10-7 Ωm |
Magnetism
Magnetism | paramagnetic |
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Chemical properties
Basicity | slightly basic |
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Oxidation state | 3 |
Standard potential | -2.3 V (Lu3+ + 3e- → Lu) |
Electronegativity
Pauling scale | 1.27 |
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Allred-Rochow scale | 1.14 |
Nagle scale | 1.12 |
Other properties
Natural occurrence | primordial |
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Crystal structure | Hexagonal close-packed |
Goldschmidt Classification | lithophile |
Superconductor | with transition tempperature (solid body, normal pressure) |
Price/kg | 643 USD |
Natural abundances
satellite_alt
Universe
0.1 ppb ≈ 1·109 M☉
sunny
Sun
1 ppb ≈ 1.98·109 Mt
destruction
Meteorite
30 ppb ≈ 30 mg
public
Earth’s crust
560 ppb ≈ 15,500 Mt
water_drop
Oceans
1.5·10-4 ppb ≈ 205 t
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Flowing water
0.008 ppb ≈ 128 t
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