71LuLutetium

Lutetium is a chemical element with the symbol Lu and atomic number 71. It is a silvery white metal, which resists corrosion in dry air, but not in moist air. Lutetium is the last element in the lanthanide series, and it is traditionally counted among the rare earth elements; it can also be classified as the first element of the 6th-period transition metals. Lutetium was independently discovered in 1907 by French scientist Georges Urbain, Austrian mineralogist Baron Carl Auer von Welsbach, and American chemist Charles James. All of these researchers found lutetium as an impurity in the mineral ytterbia, which was previously thought to consist entirely of ytterbium. The dispute on the priority of the discovery occurred shortly after, with Urbain and Welsbach accusing each other of publishing results influenced by the published research of the other; the naming honor went to Urbain, as he had published his results earlier. He chose the name lutecium for the new element, but in 1949 the spelling was changed to lutetium. In 1909, the priority was finally granted to Urbain and his names were adopted as official ones; however, the name cassiopeium (or later cassiopium) for element 71 proposed by Welsbach was used by many German scientists until the 1950s. Lutetium is not a particularly abundant element, although it is significantly more common than silver in the Earth's crust. It has few specific uses. Lutetium-176 is a relatively abundant (2. 5%) radioactive isotope with a half-life of about 38 billion years, used to determine the age of minerals and meteorites. Lutetium usually occurs in association with the element yttrium and is sometimes used in metal alloys and as a catalyst in various chemical reactions. 177Lu-DOTA-TATE is used for radionuclide therapy (see Nuclear medicine) on neuroendocrine tumours. Lutetium has the highest Brinell hardness of any lanthanide, at 890–1300 MPa.

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Atomic properties

Standard atomic weight174.966 ±1·10-4
Atomic mass174.966 u

Atomic radii

Radius (empirical)174 pm
Radius (calculated)217 pm
Covalent radius187 ±8 pm

Atomic shell

Electron configurationXe 4f14 5d1 6s2
Ionization energy(1st) 5.425871 eV
(2nd) 14.13 eV
(3rd) 20.9594 eV
(4th) 45.249 eV
(5th) 66.8 eV
Shell model
Electrons
k-shell:2
l-shell:8
m-shell:18
n-shell:32
o-shell:9
p-shell:2

Physical properties

Phasesolid
Density9.84 g·cm−3 (298.1 K)
Molar volume1.778·10-5 m3·mol−1

Temperatures

Melting point1,925 K
Boiling point3,675 K
Liquid range1,750 K
Transition temperature0.1 K

Enthalpies

Melting enthalpy(22 kJ·mol-1)
Enthalpy of vaporization415 kJ·mol-1
Binding energy428 kJ·mol-1

Heat and conductivity

Thermal conductivity16 W·m-1·K-1
Expansion coefficient9.9·10-6 K-1

Hardnesses

Brinell hardness893 NM·m-2
Vickers hardness1,160 NM·m-2

Elastic properties

Young’s modulus69 GPa
Shear modulus27 GPa
Bulk modulus48 GPa
Poisson’s ratio0.26

Electrical properties

Electrical conductivity1.72·106 S·m-1
Resistance5.8·10-7 Ωm

Magnetism

Magnetismparamagnetic

Chemical properties

Basicityslightly basic
Oxidation state3
Standard potential-2.3 V (Lu3+ + 3e- → Lu)

Electronegativity

Pauling scale1.27
Allred-Rochow scale1.14
Nagle scale1.12

Other properties

Natural occurrenceprimordial
Crystal structureHexagonal close-packed
Goldschmidt Classificationlithophile
Superconductorwith transition tempperature (solid body, normal pressure)
Price/kg643 USD

Natural abundances

satellite_alt
Universe
0.1 ppb ≈ 1·109 M☉
sunny
Sun
1 ppb ≈ 1.98·109 Mt
destruction
Meteorite
30 ppb ≈ 30 mg
public
Earth’s crust
560 ppb ≈ 15,500 Mt
water_drop
Oceans
1.5·10-4 ppb ≈ 205 t
waves
Flowing water
0.008 ppb ≈ 128 t
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