21ScScandium

Scandium is a chemical element with the symbol Sc and atomic number 21. It is a silvery-white metallic d-block element. Historically, it has been classified as a rare-earth element, together with yttrium and the lanthanides. It was discovered in 1879 by spectral analysis of the minerals euxenite and gadolinite from Scandinavia. Scandium is present in most of the deposits of rare-earth and uranium compounds, but it is extracted from these ores in only a few mines worldwide. Because of the low availability and difficulties in the preparation of metallic scandium, which was first done in 1937, applications for scandium were not developed until the 1970s, when the positive effects of scandium on aluminium alloys were discovered. To this day, its use in such alloys remains its only major application. The global trade of scandium oxide is 15–20 tonnes per year. The properties of scandium compounds are intermediate between those of aluminium and yttrium. A diagonal relationship exists between the behavior of magnesium and scandium, just as there is between beryllium and aluminium. In the chemical compounds of the elements in group 3, the predominant oxidation state is +3.

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Atomic properties

Standard atomic weight44.9559 ±4·10-6
Atomic mass44.9559 u

Atomic radii

Radius (empirical)162 pm
Radius (calculated)184 pm
Covalent radius170 ±7 pm
Van der Waals radius211 pm

Atomic shell

Electron configurationAr 3d1 4s2
Ionization energy(1st) 6.56149 eV
(2nd) 12.79977 eV
(3rd) 24.756838 eV
(4th) 73.4894 eV
(5th) 91.95 eV
Shell model
Electrons
k-shell:2
l-shell:8
m-shell:9
n-shell:2

Physical properties

Phasesolid
Density2.985 g·cm−3
Molar volume1.5·10-5 m3·mol−1

Temperatures

Melting point1,814 K
Boiling point3,109 K
Liquid range1,295 K
Transition temperature0.34 K

Enthalpies

Melting enthalpy16 kJ·mol-1
Enthalpy of vaporization318 kJ·mol-1
Binding energy378 kJ·mol-1

Heat and conductivity

Specific heat capacity586 J·kg−1·K−1
Thermal conductivity16 W·m-1·K-1
Expansion coefficient1.02·10-5 K-1

Hardnesses

Mohs hardness2.5
Brinell hardness750 NM·m-2

Elastic properties

Young’s modulus74 GPa
Shear modulus29 GPa
Bulk modulus57 GPa
Poisson’s ratio0.28

Electrical properties

Electrical conductivity1.81·106 S·m-1
Resistance5.5·10-7 Ωm

Magnetism

Magnetismparamagnetic
Magnetic susceptibility3.15·10-4 cm3·mol−1 (292 K)

Chemical properties

Basicityslightly basic
Oxidation state3
Standard potential-2.03 V (Sc3+ + 3e- → Sc)

Electronegativity

Pauling scale1.36
Sanderson scale1.02
Allred-Rochow scale1.2
Ghosh-Gupta scale2.857 eV
Nagle scale1.17
Pearson absolute negativity3.34 eV

Other properties

Natural occurrenceprimordial
Crystal structureHexagonal close-packed
Goldschmidt Classificationlithophile
Superconductorwith transition tempperature under special conditions
Price/kg3,460 USD

Natural abundances

satellite_alt
Universe
30 ppb ≈ 3.01·1011 M☉
sunny
Sun
40 ppb ≈ 7.95·1010 Mt
destruction
Meteorite
6,500 ppb ≈ 6.5 g
public
Earth’s crust
26,000 ppb ≈ 720,000 Mt
water_drop
Oceans
0.0015 ppb ≈ 2.05 kt
waves
Flowing water
0.004 ppb ≈ 64 t
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