40ZrZirconium

Zirconium is a chemical element; it has symbol Zr and atomic number 40. First identified in 1789, isolated in impure form in 1824, and manufactured at scale by 1925, pure zirconium is a lustrous transition metal with a greyish-white color that closely resembles hafnium and, to a lesser extent, titanium. It is solid at room temperature, ductile, malleable and corrosion-resistant. The name zirconium is derived from the name of the mineral zircon, the most important source of zirconium. The word is related to Persian zargun (zircon; zar-gun, "gold-like" or "as gold"). Besides zircon, zirconium occurs in over 140 other minerals, including baddeleyite and eudialyte; most zirconium is produced as a byproduct of minerals mined for titanium and tin.

Zirconium forms a variety of inorganic compounds, such as zirconium dioxide, and organometallic compounds, such as zirconocene dichloride. Five isotopes occur naturally, four of which are stable. The metal and its alloys are mainly used as a refractory and opacifier; zirconium alloys are used to clad nuclear fuel rods due to their low neutron absorption and strong resistance to corrosion, and in space vehicles and turbine blades where high heat resistance is necessary. Zirconium also finds uses in flashbulbs, biomedical applications such as dental implants and prosthetics, deodorant, and water purification systems.

Zirconium compounds have no known biological role, though the element is widely distributed in nature and appears in small quantities in biological systems without adverse effects. There is no indication of zirconium as a carcinogen. The main hazards posed by zirconium are flammability in powder form and irritation of the eyes.

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Atomic properties

Standard atomic weight91.224 ±0.002
Atomic mass91.2242 u

Atomic radii

Radius (empirical)160 pm
Radius (calculated)206 pm
Covalent radius175 ±7 pm

Atomic shell

Electron configurationKr 4d2 5s2
Ionization energy(1st) 6.634126 eV
(2nd) 13.13 eV
(3rd) 23.17 eV
(4th) 34.41836 eV
(5th) 80.348 eV
Shell model
Electrons
k-shell:2
l-shell:8
m-shell:18
n-shell:10
o-shell:2

Physical properties

Phasesolid
Density6.501 g·cm−3 (298.1 K)
Molar volume1.402·10-5 m3·mol−1
Speed of sound3,800 m·s−1

Temperatures

Melting point2,125 K
Boiling point4,650 K
Liquid range2,525 K
Transition temperature0.6 K

Enthalpies

Melting enthalpy21 kJ·mol-1
Enthalpy of vaporization580 kJ·mol-1
Binding energy605 kJ·mol-1

Heat and conductivity

Specific heat capacity270 J·kg−1·K−1
Thermal conductivity22.7 W·m-1·K-1
Expansion coefficient5.7·10-6 K-1

Hardnesses

Mohs hardness5
Brinell hardness650 NM·m-2
Vickers hardness903 NM·m-2

Elastic properties

Young’s modulus68 GPa
Shear modulus33 GPa
Poisson’s ratio0.34

Electrical properties

Electrical conductivity2.36·106 S·m-1
Resistance4.33·10-7 Ωm

Magnetism

Magnetismparamagnetic

Chemical properties

Basicityamphoteric
Oxidation state4, 2
Standard potential-1.553 V (ZrO2 + 4H+ + 4e- → Zr + 2H2O)

Electronegativity

Pauling scale1.33
Sanderson scale0.9
Allred-Rochow scale1.22
Ghosh-Gupta scale2.848 eV
Nagle scale1.17
Pearson absolute negativity3.64 eV

Other properties

Natural occurrenceprimordial
Crystal structureHexagonal close-packed
Goldschmidt Classificationlithophile
Superconductorwith transition temperature (solid body, normal pressure)
Price/kg36.4 ±0.7 USD

Natural abundances

satellite_alt
Universe
50 ppb ≈ 5.02·1011 M☉
sunny
Sun
40 ppb ≈ 7.95·1010 Mt
destruction
Meteorite
6,700 ppb ≈ 6.7 g
public
Earth’s crust
130,000 ppb ≈ 3.6·106 Mt
water_drop
Oceans
0.026 ppb ≈ 35.6 kt
waves
Flowing water
3 ppb ≈ 48 kt
accessibility_new
Human body
50 ppb ≈ 3.5 mg