59PrPraseodymium

Praseodymium is a chemical element with the symbol Pr and the atomic number 59. It is the third member of the lanthanide series and is considered one of the rare-earth metals. It is a soft, silvery, malleable and ductile metal, valued for its magnetic, electrical, chemical, and optical properties. It is too reactive to be found in native form, and pure praseodymium metal slowly develops a green oxide coating when exposed to air.

Praseodymium always occurs naturally together with the other rare-earth metals. It is the sixth-most abundant rare-earth element and fourth-most abundant lanthanide, making up 9. 1 parts per million of the Earth's crust, an abundance similar to that of boron. In 1841, Swedish chemist Carl Gustav Mosander extracted a rare-earth oxide residue he called didymium from a residue he called "lanthana", in turn separated from cerium salts. In 1885, the Austrian chemist Carl Auer von Welsbach separated didymium into two elements that gave salts of different colours, which he named praseodymium and neodymium. The name praseodymium comes from the Ancient Greek πράσινος (prasinos), meaning 'leek-green', and δίδυμος (didymos) 'twin'.

Like most rare-earth elements, praseodymium most readily forms the +3 oxidation state, which is the only stable state in aqueous solution, although the +4 oxidation state is known in some solid compounds and, uniquely among the lanthanides, the +5 oxidation state is attainable in matrix-isolation conditions. The 0, +1, and +2 oxidation states are rarely found. Aqueous praseodymium ions are yellowish-green, and similarly, praseodymium results in various shades of yellow-green when incorporated into glasses. Many of praseodymium's industrial uses involve its ability to filter yellow light from light sources.

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Atomic properties

Standard atomic weight140.907 ±1·10-5
Atomic mass140.907 u

Atomic radii

Radius (empirical)182 pm
Radius (calculated)247 pm
Covalent radius203 ±7 pm

Atomic shell

Electron configurationXe 4f3 6s2
Ionization energy(1st) 5.4702 eV
(2nd) 10.631 eV
(3rd) 21.6237 eV
(4th) 39.981 eV
(5th) 57.53 eV
Shell model
Electrons
k-shell:2
l-shell:8
m-shell:18
n-shell:21
o-shell:8
p-shell:2

Physical properties

Phasesolid
Density6.475 g·cm−3 (298.1 K)
Molar volume2.08·10-5 m3·mol−1
Speed of sound2,280 m·s−1 (293.1 K)

Temperatures

Melting point1,208 K
Boiling point3,403 K
Liquid range2,195 K

Enthalpies

Melting enthalpy6.9 kJ·mol-1
Enthalpy of vaporization330 kJ·mol-1
Binding energy356 kJ·mol-1

Heat and conductivity

Thermal conductivity13 W·m-1·K-1
Expansion coefficient6.7·10-6 K-1

Hardnesses

Brinell hardness481 NM·m-2
Vickers hardness400 NM·m-2

Elastic properties

Young’s modulus37 GPa
Shear modulus15 GPa
Bulk modulus29 GPa
Poisson’s ratio0.28

Electrical properties

Electrical conductivity1.43·106 S·m-1
Resistance7·10-7 Ωm

Magnetism

Magnetismparamagnetic
Magnetic susceptibility0.00501 cm3·mol−1 (293 K)

Chemical properties

Basicityslightly basic
Oxidation state3, 4, 2
Standard potential-2.35 V (Pr3+ + 3e- → Pr)

Electronegativity

Pauling scale1.13
Allred-Rochow scale1.07
Nagle scale1.06

Other properties

Natural occurrenceprimordial
Crystal structureDouble hexagonal close-packed
Goldschmidt Classificationlithophile
Superconductorwithout transition tempperature
Price/kg103 USD

Natural abundances

satellite_alt
Universe
2 ppb ≈ 2.01·1010 M☉
sunny
Sun
1 ppb ≈ 1.98·109 Mt
destruction
Meteorite
100 ppb ≈ 100 mg
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Earth’s crust
8,700 ppb ≈ 240,000 Mt
water_drop
Oceans
6·10-4 ppb ≈ 822 t
waves
Flowing water
0.03 ppb ≈ 480 t
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