65TbTerbium

Terbium is a chemical element with the symbol Tb and atomic number 65. It is a silvery-white, rare earth metal that is malleable, and ductile. The ninth member of the lanthanide series, terbium is a fairly electropositive metal that reacts with water, evolving hydrogen gas. Terbium is never found in nature as a free element, but it is contained in many minerals, including cerite, gadolinite, monazite, xenotime and euxenite.

Swedish chemist Carl Gustaf Mosander discovered terbium as a chemical element in 1843. He detected it as an impurity in yttrium oxide, Y2O3. Yttrium and terbium, as well as erbium and ytterbium, are named after the village of Ytterby in Sweden. Terbium was not isolated in pure form until the advent of ion exchange techniques.

Terbium is used to dope calcium fluoride, calcium tungstate and strontium molybdate in solid-state devices, and as a crystal stabilizer of fuel cells that operate at elevated temperatures. As a component of Terfenol-D (an alloy that expands and contracts when exposed to magnetic fields more than any other alloy), terbium is of use in actuators, in naval sonar systems and in sensors.

Most of the world's terbium supply is used in green phosphors. Terbium oxide is used in fluorescent lamps and television and monitor cathode-ray tubes (CRTs). Terbium green phosphors are combined with divalent europium blue phosphors and trivalent europium red phosphors to provide trichromatic lighting technology, a high-efficiency white light used for standard illumination in indoor lighting.

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Atomic properties

Standard atomic weight158.925 ±7·10-6
Atomic mass158.925 u

Atomic radii

Radius (empirical)177 pm
Radius (calculated)225 pm
Covalent radius194 ±5 pm

Atomic shell

Electron configurationXe 4f9 6s2
Ionization energy(1st) 5.8638 eV
(2nd) 11.513 eV
(3rd) 21.82 eV
(4th) 39.33 eV
(5th) 66.5 eV
Shell model
Electrons
k-shell:2
l-shell:8
m-shell:18
n-shell:27
o-shell:8
p-shell:2

Physical properties

Phasesolid
Density8.253 g·cm−3 (298.1 K)
Molar volume1.93·10-5 m3·mol−1
Speed of sound2,620 m·s−1 (293.1 K)

Temperatures

Melting point1,629 K
Boiling point3,396 K
Liquid range1,767 K

Enthalpies

Melting enthalpy10.8 kJ·mol-1
Enthalpy of vaporization295 kJ·mol-1
Binding energy389 kJ·mol-1

Heat and conductivity

Thermal conductivity11 W·m-1·K-1
Expansion coefficient1.03·10-5 K-1

Hardnesses

Brinell hardness677 NM·m-2
Vickers hardness863 NM·m-2

Elastic properties

Young’s modulus56 GPa
Shear modulus22 GPa
Bulk modulus38.7 GPa
Poisson’s ratio0.26

Electrical properties

Electrical conductivity870,000 S·m-1
Resistance1.15·10-6 Ωm

Magnetism

Magnetismparamagnetic
Magnetic susceptibility0.146 cm3·mol−1 (273 K)

Chemical properties

Basicityslightly basic
Oxidation state4, 3

Electronegativity

Allred-Rochow scale1.1
Nagle scale1.08

Other properties

Natural occurrenceprimordial
Crystal structureHexagonal close-packed
Goldschmidt Classificationlithophile
Superconductorwithout transition tempperature
Price/kg658 USD

Natural abundances

satellite_alt
Universe
0.5 ppb ≈ 5.02·109 M☉
sunny
Sun
0.1 ppb ≈ 1.98·108 Mt
destruction
Meteorite
40 ppb ≈ 40 mg
public
Earth’s crust
940 ppb ≈ 26,000 Mt
water_drop
Oceans
1.4·10-4 ppb ≈ 191 t
waves
Flowing water
0.008 ppb ≈ 128 t
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