74WTungsten

Tungsten (also called wolfram) is a chemical element with the symbol W and atomic number 74. Tungsten is a rare metal found naturally on Earth almost exclusively as compounds with other elements. It was identified as a new element in 1781 and first isolated as a metal in 1783. Its important ores include scheelite and wolframite, the latter lending the element its alternate name.

The free element is remarkable for its robustness, especially the fact that it has the highest melting point of all known elements, melting at 3,422 °C (6,192 °F; 3,695 K). It also has the highest boiling point, at 5,930 °C (10,706 °F; 6,203 K). Its density is 19. 30 grams per cubic centimetre (0. 697 lb/cu in), comparable with that of uranium and gold, and much higher (about 1. 7 times) than that of lead. Polycrystalline tungsten is an intrinsically brittle and hard material (under standard conditions, when uncombined), making it difficult to work into metal. However, pure single-crystalline tungsten is more ductile and can be cut with a hard-steel hacksaw. Tungsten occurs in many alloys, which have numerous applications, including incandescent light bulb filaments, X-ray tubes, electrodes in gas tungsten arc welding, superalloys, and radiation shielding. Tungsten's hardness and high density make it suitable for military applications in penetrating projectiles. Tungsten compounds are often used as industrial catalysts.

Tungsten is the only metal in the third transition series that is known to occur in biomolecules, being found in a few species of bacteria and archaea. However, tungsten interferes with molybdenum and copper metabolism and is somewhat toxic to most forms of animal life.

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Atomic properties

Standard atomic weight183.84 ±0.01
Atomic mass183.841 u

Atomic radii

Radius (empirical)139 pm
Radius (calculated)193 pm
Covalent radius162 ±7 pm

Atomic shell

Electron configurationXe 4f14 5d4 6s2
Ionization energy(1st) 7.86403 eV
(2nd) 16.37 eV
(3rd) 26 eV
(4th) 38.2 eV
(5th) 51.6 eV
Shell model
Electrons
k-shell:2
l-shell:8
m-shell:18
n-shell:32
o-shell:12
p-shell:2

Physical properties

Phasesolid
Density19.25 g·cm−3 (293.1 K)
Molar volume9.47·10-6 m3·mol−1
Speed of sound5,174 m·s−1

Temperatures

Melting point3,695 K
Boiling point6,203 K
Liquid range2,508 K
Transition temperature0.01 K

Enthalpies

Melting enthalpy35 kJ·mol-1
Enthalpy of vaporization800 kJ·mol-1
Binding energy860 kJ·mol-1

Heat and conductivity

Specific heat capacity138 J·kg−1·K−1
Thermal conductivity170 W·m-1·K-1
Expansion coefficient4.5·10-6 K-1
Work function4.55 eV

Hardnesses

Mohs hardness7.5
Brinell hardness2,570 NM·m-2
Vickers hardness3,430 NM·m-2

Elastic properties

Young’s modulus411 GPa
Shear modulus161 GPa
Bulk modulus310 GPa
Poisson’s ratio0.28

Electrical properties

Electrical conductivity1.85·107 S·m-1
Resistance5.4·10-8 Ωm

Magnetism

Magnetismparamagnetic
Magnetic susceptibility5.9·10-5 cm3·mol−1 (298 K)

Optical properties

Reflectivity62 %

Chemical properties

Basicityslightly acidic
Oxidation state6, 5, 4, 3, 2
Standard potential-0.119 V (WO2 + 4H+ + 4e- → W + 2H2O)

Electronegativity

Pauling scale2.36
Sanderson scale0.98
Allred-Rochow scale1.4
Nagle scale1.31
Pearson absolute negativity4.4 eV

Other properties

Natural occurrenceprimordial
Crystal structureBody-centered cubic
Goldschmidt Classificationsiderophile
Superconductorwith transition tempperature (solid body, normal pressure)
Price/kg35.3 USD

Natural abundances

satellite_alt
Universe
0.5 ppb ≈ 5.02·109 M☉
sunny
Sun
4 ppb ≈ 7.95·109 Mt
destruction
Meteorite
120 ppb ≈ 120 mg
public
Earth’s crust
1,100 ppb ≈ 30,400 Mt
water_drop
Oceans
0.12 ppb ≈ 164 kt
waves
Flowing water
0.03 ppb ≈ 480 t
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