62SmSamarium

Samarium is a chemical element with symbol Sm and atomic number 62. It is a moderately hard silvery metal that slowly oxidizes in air. Being a typical member of the lanthanide series, samarium usually has the oxidation state +3. Compounds of samarium(II) are also known, most notably the monoxide SmO, monochalcogenides SmS, SmSe and SmTe, as well as samarium(II) iodide.

Discovered in 1879 by French chemist Paul-Émile Lecoq de Boisbaudran, samarium was named after the mineral samarskite from which it was isolated. The mineral itself was named after a Russian mine official, Colonel Vassili Samarsky-Bykhovets, who thus became the first person to have a chemical element named after him, albeit indirectly.

Samarium is the 40th most abundant element in Earth's crust and more common than metals such as tin. It occurs in concentration up to 2. 8% in several minerals including cerite, gadolinite, samarskite, monazite and bastnäsite, the last two being the most common commercial sources of the element. These minerals are mostly found in China, the United States, Brazil, India, Sri Lanka and Australia; China is by far the world leader in samarium mining and production.

The main commercial use of samarium is in samarium–cobalt magnets, which have permanent magnetization second only to neodymium magnets; however, samarium compounds can withstand significantly higher temperatures, above 700 °C (1,292 °F), without losing their permanent magnetic properties. The radioisotope samarium-153 is the active component of the drug samarium (153Sm) lexidronam (Quadramet), which kills cancer cells in lung cancer, prostate cancer, breast cancer and osteosarcoma. Another isotope, samarium-149, is a strong neutron absorber and so is added to control rods of nuclear reactors. It also forms as a decay product during the reactor operation and is one of the important factors considered in the reactor design and operation. Other uses of samarium include catalysis of chemical reactions, radioactive dating and X-ray lasers. Samarium(II) iodide, in particular, is a common reducing agent in chemical synthesis.

Samarium has no biological role; some samarium salts are slightly toxic.

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Atomic properties

Standard atomic weight150.36 ±0.02
Atomic mass150.362 u

Atomic radii

Radius (empirical)180 pm
Radius (calculated)238 pm
Covalent radius198 ±8 pm

Atomic shell

Electron configurationXe 4f6 6s2
Ionization energy(1st) 5.64371 eV
(2nd) 11.078 eV
(3rd) 23.55 eV
(4th) 41.64 eV
(5th) 62.7 eV
Shell model
Electrons
k-shell:2
l-shell:8
m-shell:18
n-shell:24
o-shell:8
p-shell:2

Physical properties

Phasesolid
Density7.536 g·cm−3 (298.1 K)
Molar volume1.998·10-5 m3·mol−1
Speed of sound2,130 m·s−1 (293.1 K)

Temperatures

Melting point1,345 K
Boiling point2,173 K
Liquid range828 K

Enthalpies

Melting enthalpy8.6 kJ·mol-1
Enthalpy of vaporization175 kJ·mol-1
Binding energy207 kJ·mol-1

Heat and conductivity

Thermal conductivity13 W·m-1·K-1
Expansion coefficient1.27·10-5 K-1

Hardnesses

Brinell hardness441 NM·m-2
Vickers hardness412 NM·m-2

Elastic properties

Young’s modulus50 GPa
Shear modulus20 GPa
Bulk modulus38 GPa
Poisson’s ratio0.27

Electrical properties

Electrical conductivity1.06·106 S·m-1
Resistance9.4·10-7 Ωm

Magnetism

Magnetismparamagnetic
Magnetic susceptibility0.00186 cm3·mol−1 (291 K)

Chemical properties

Basicityslightly basic
Oxidation state2, 3

Electronegativity

Pauling scale1.17
Allred-Rochow scale1.07
Nagle scale1.05

Other properties

Natural occurrenceprimordial
Crystal structureRhombohedral
Goldschmidt Classificationlithophile
Superconductorwithout transition tempperature
Price/kg13.9 USD

Natural abundances

satellite_alt
Universe
5 ppb ≈ 5.02·1010 M☉
sunny
Sun
1 ppb ≈ 1.98·109 Mt
destruction
Meteorite
170 ppb ≈ 170 mg
public
Earth’s crust
6,000 ppb ≈ 166,000 Mt
water_drop
Oceans
4.5·10-4 ppb ≈ 616 t
waves
Flowing water
0.03 ppb ≈ 480 t
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