56BaBarium

Barium is a chemical element with the symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element.

The most common minerals of barium are baryte (barium sulfate, BaSO4) and witherite (barium carbonate, BaCO3). The name barium originates from the alchemical derivative "baryta", from Greek βαρὺς (barys), meaning 'heavy'. Baric is the adjectival form of barium. Barium was identified as a new element in 1772, but not reduced to a metal until 1808 with the advent of electrolysis.

Barium has few industrial applications. Historically, it was used as a getter for vacuum tubes and in oxide form as the emissive coating on indirectly heated cathodes. It is a component of YBCO (high-temperature superconductors) and electroceramics, and is added to steel and cast iron to reduce the size of carbon grains within the microstructure. Barium compounds are added to fireworks to impart a green color. Barium sulfate is used as an insoluble additive to oil well drilling fluid. In a purer form it is used as X-ray radiocontrast agents for imaging the human gastrointestinal tract. Water-soluble barium compounds are poisonous and have been used as rodenticides.

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Atomic properties

Standard atomic weight137.327 ±0.007
Atomic mass137.327 u

Atomic radii

Radius (empirical)222 pm
Radius (calculated)253 pm
Covalent radius215 ±11 pm
Van der Waals radius268 pm

Atomic shell

Electron configurationXe 6s2
Ionization energy(1st) 5.2116646 eV
(2nd) 10.003826 eV
(3rd) 35.8438 eV
(4th) 47 eV
(5th) 58 eV
Shell model
Electrons
k-shell:2
l-shell:8
m-shell:18
n-shell:18
o-shell:8
p-shell:2

Physical properties

Phasesolid
Density3.62 g·cm−3 (293 K)
Molar volume3.816·10-5 m3·mol−1
Speed of sound1,620 m·s−1

Temperatures

Melting point1,000 K
Boiling point2,118 K
Liquid range1,118 K
Transition temperature5 K

Enthalpies

Melting enthalpy8 kJ·mol-1
Enthalpy of vaporization140 kJ·mol-1
Binding energy182 kJ·mol-1

Heat and conductivity

Thermal conductivity18 W·m-1·K-1
Expansion coefficient2.06·10-5 K-1
Work function2.7 [1.8 … 2.52] eV

Hardnesses

Mohs hardness1.25

Elastic properties

Young’s modulus13 GPa
Shear modulus4.9 GPa
Bulk modulus9.6 GPa

Electrical properties

Electrical conductivity2.94·106 S·m-1
Resistance3.4·10-7 Ωm

Magnetism

Magnetismparamagnetic
Magnetic susceptibility2.06·10-5 cm3·mol−1

Chemical properties

Basicitybasic
Oxidation state+2
Standard potential-2.92 V (Ba2+ + 2e- → Ba)

Electronegativity

Pauling scale0.89
Sanderson scale0.68
Allred-Rochow scale0.97
Mulliken scale0.88
Nagle scale0.98
Pearson absolute negativity2.4 eV

Other properties

Natural occurrenceprimordial
Crystal structureBody-centered cubic
Goldschmidt Classificationlithophile
Superconductorwith transition tempperature under special conditions
Price/kg0.26 ±0.015 USD

Natural abundances

satellite_alt
Universe
10 ppb ≈ 1·1011 M☉
sunny
Sun
10 ppb ≈ 1.98·1010 Mt
destruction
Meteorite
2,800 ppb ≈ 2.8 g
public
Earth’s crust
340,000 ppb ≈ 9.41·106 Mt
water_drop
Oceans
30 ppb ≈ 41.1 Gt
waves
Flowing water
25 ppb ≈ 400 kt
accessibility_new
Human body
300 ppb ≈ 21 mg