69TmThulium

Thulium is a chemical element; it has symbol Tm and atomic number 69. It is the thirteenth element in the lanthanide series of metals. It is the second-least abundant lanthanide in the Earth's crust, after radioactively unstable promethium. It is an easily workable metal with a bright silvery-gray luster. It is fairly soft and slowly tarnishes in air. Despite its high price and rarity, thulium is used as a dopant in solid-state lasers. It has no significant biological role and is not particularly toxic. Artificial radioactive isotopes of thulium are used as radiation sources in some portable X-ray devices.

In 1879, the Swedish chemist Per Teodor Cleve separated two previously unknown components, which he called holmia and thulia, from the rare-earth mineral erbia; these were the oxides of holmium and thulium, respectively. His example of thulium oxide contained impurities of ytterbium oxide. A relatively pure sample of thulium oxide was first obtained in 1911. The metal itself was first obtained in 1936 by Wilhelm Klemm and Heinrich Bommer.

Like the other lanthanides, its most common oxidation state is +3, seen in its oxide, halides and other compounds. In aqueous solution, like compounds of other late lanthanides, soluble thulium compounds form coordination complexes with nine water molecules.

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Atomic properties

Standard atomic weight168.934 ±5·10-6
Atomic mass168.934 u

Atomic radii

Radius (empirical)176 pm
Radius (calculated)222 pm
Covalent radius190 ±10 pm

Atomic shell

Electron configurationXe 4f13 6s2
Ionization energy(1st) 6.18431 eV
(2nd) 12.065 eV
(3rd) 23.66 eV
(4th) 42.41 eV
(5th) 65.4 eV
Shell model
Electrons
k-shell:2
l-shell:8
m-shell:18
n-shell:31
o-shell:8
p-shell:2

Physical properties

Phasesolid
Density9.318 g·cm−3 (298.1 K)
Molar volume1.91·10-5 m3·mol−1

Temperatures

Melting point1,818 K
Boiling point2,223 K
Liquid range405 K

Enthalpies

Melting enthalpy16.8 kJ·mol-1
Enthalpy of vaporization250 kJ·mol-1
Binding energy232 kJ·mol-1

Heat and conductivity

Thermal conductivity16.8 W·m-1·K-1
Expansion coefficient1.33·10-5 K-1

Hardnesses

Brinell hardness471 NM·m-2
Vickers hardness520 NM·m-2

Elastic properties

Young’s modulus74 GPa
Shear modulus31 GPa
Bulk modulus45 GPa
Poisson’s ratio0.21

Electrical properties

Electrical conductivity1.48·106 S·m-1
Resistance6.76·10-7 Ωm

Magnetism

Magnetismparamagnetic
Curie point25 K
Neel temperature56 K
Magnetic susceptibility0.0255 cm3·mol−1 (291 K)

Chemical properties

Basicityslightly basic
Oxidation state2, 3, 4
Standard potential-2.32 V (Tm3+ + 3e- → Tm)

Electronegativity

Pauling scale1.25
Allred-Rochow scale1.11
Nagle scale1.12

Other properties

Natural occurrenceprimordial
Crystal structureHexagonal close-packed
Goldschmidt Classificationlithophile
Superconductorwithout transition temperature
Price/kg3,000 USD

Natural abundances

satellite_alt
Universe
0.1 ppb ≈ 1·109 M☉
sunny
Sun
0.2 ppb ≈ 3.97·108 Mt
destruction
Meteorite
30 ppb ≈ 30 mg
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Earth’s crust
450 ppb ≈ 12,400 Mt
water_drop
Oceans
2·10-4 ppb ≈ 274 t
waves
Flowing water
0.009 ppb ≈ 144 t
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