83BiBismuth

Bismuth is a chemical element with the symbol Bi and atomic number 83. It is a post-transition metal and one of the pnictogens, with chemical properties resembling its lighter group 15 siblings arsenic and antimony. Elemental bismuth occurs naturally, and its sulfide and oxide forms are important commercial ores. The free element is 86% as dense as lead. It is a brittle metal with a silvery-white color when freshly produced. Surface oxidation generally gives samples of the metal a somewhat rosy cast. Further oxidation under heat can give bismuth a vividly iridescent appearance due to thin-film interference. Bismuth is both the most diamagnetic element and one of the least thermally conductive metals known.

Bismuth was long considered the element with the highest atomic mass whose nuclei do not spontaneously decay. However, in 2003 it was discovered to be extremely weakly radioactive. The metal's only primordial isotope, bismuth-209, experiences alpha decay at such a rate that its half-life is more than the estimated age of the universe. Bismuth metal has been known since ancient times. Before modern analytical methods bismuth's metallurgical similarities to lead and tin often led it to be confused with those metals. The etymology of "bismuth" is uncertain. The name may come from mid-sixteenth century Neo-Latin translations of the German words weiße Masse or Wismuth, meaning 'white mass', which were rendered as bisemutum or bisemutium.

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Atomic properties

Standard atomic weight208.98 ±1·10-5
Atomic mass208.98 u

Atomic radii

Radius (empirical)156 pm
Radius (calculated)143 pm
Covalent radius148 ±4 pm
Van der Waals radius207 pm

Atomic shell

Electron configurationXe 4f14 5d10 6s2 6p3
Ionization energy(1st) 7.285516 eV
(2nd) 16.703 eV
(3rd) 25.563 eV
(4th) 45.37 eV
(5th) 54.856 eV
Shell model
Electrons
k-shell:2
l-shell:8
m-shell:18
n-shell:32
o-shell:18
p-shell:5

Physical properties

Phasesolid
Density9.78 g·cm−3
Molar volume2.131·10-5 m3·mol−1
Speed of sound1,790 m·s−1 (293.1 K)

Temperatures

Melting point544.7 K
Boiling point1,837 K
Liquid range1,292 K
Transition temperature8.7 K

Enthalpies

Melting enthalpy10.9 kJ·mol-1
Enthalpy of vaporization160 kJ·mol-1
Binding energy207 kJ·mol-1

Heat and conductivity

Thermal conductivity8 W·m-1·K-1
Expansion coefficient1.34·10-5 K-1

Hardnesses

Mohs hardness2.25
Brinell hardness94.2 NM·m-2

Elastic properties

Young’s modulus32 GPa
Shear modulus12 GPa
Bulk modulus31 GPa
Poisson’s ratio0.33

Electrical properties

Electrical conductivity769,000 S·m-1
Resistance1.3·10-6 Ωm

Magnetism

Magnetismdiamagnetic
Magnetic susceptibility-2.8·10-4 cm3·mol−1

Chemical properties

Basicityslightly acidic
Oxidation state(-3), 1, 3, 5
Standard potential0.317 V (Bi3+ + 3e- → Bi)

Electronegativity

Pauling scale2.02
Sanderson scale2.34
Allred-Rochow scale1.67
Mulliken scale2.15
Nagle scale1.83
Pearson absolute negativity4.69 eV

Other properties

Natural occurrenceprimordial
Crystal structureRhombohedral
Goldschmidt Classificationchalcophile
Superconductorwith transition tempperature under special conditions
Radioactivityslightly radioactive
Price/kg6.36 USD

Natural abundances

satellite_alt
Universe
0.7 ppb ≈ 7.03·109 M☉
sunny
Sun
10 ppb ≈ 1.98·1010 Mt
destruction
Meteorite
70 ppb ≈ 70 mg
public
Earth’s crust
25 ppb ≈ 692 Mt
water_drop
Oceans
0.02 ppb ≈ 27.4 kt
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