84PoPolonium

Polonium is a chemical element with the symbol Po and atomic number 84. A rare and highly radioactive metal with no stable isotopes, polonium is a chalcogen and chemically similar to selenium and tellurium, though its metallic character resembles that of its horizontal neighbors in the periodic table: thallium, lead, and bismuth. Due to the short half-life of all its isotopes, its natural occurrence is limited to tiny traces of the fleeting polonium-210 (with a half-life of 138 days) in uranium ores, as it is the penultimate daughter of natural uranium-238. Though longer-lived isotopes exist, such as the 125. 2 years half-life of polonium 209, they are much more difficult to produce. Today, polonium is usually produced in milligram quantities by the neutron irradiation of bismuth. Due to its intense radioactivity, which results in the radiolysis of chemical bonds and radioactive self-heating, its chemistry has mostly been investigated on the trace scale only.

Polonium was discovered in July 1898 by Marie Skłodowska-Curie and Pierre Curie, when it was extracted from the uranium ore pitchblende and identified solely by its strong radioactivity: it was the first element to be so discovered. Polonium was named after Marie Curie's homeland of Poland. Polonium has few applications, and those are related to its radioactivity: heaters in space probes, antistatic devices, sources of neutrons and alpha particles, and poison. It is extremely dangerous to humans.

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Atomic properties

Atomic mass(209.98 u)

Atomic radii

Radius (empirical)168 pm
Radius (calculated)135 pm
Covalent radius140 ±4 pm
Van der Waals radius197 pm

Atomic shell

Electron configurationXe 4f14 5d10 6s2 6p4
Ionization energy(1st) 8.41807 eV
(2nd) 19.3 eV
(3rd) 27.3 eV
(4th) 36 eV
(5th) 57 eV
(6th) 69.1 eV
Shell model
Electrons
k-shell:2
l-shell:8
m-shell:18
n-shell:32
o-shell:18
p-shell:6

Physical properties

Phasesolid
Density9.196 g·cm−3
Molar volume2.297·10-5 m3·mol−1

Temperatures

Melting point527 K
Boiling point1,235 K
Liquid range708 K

Enthalpies

Melting enthalpy(13 kJ·mol-1)
Enthalpy of vaporization(100 kJ·mol-1)
Binding energy142 kJ·mol-1

Heat and conductivity

Thermal conductivity20 W·m-1·K-1

Electrical properties

Electrical conductivity2.5·106 S·m-1
Resistance4·10-7 Ωm

Magnetism

Magnetismnonmagnetic

Chemical properties

Basicityamphoteric
Oxidation state(-2), 2, 4, 6
Standard potential0.37 V (Po2+ + 2e- → Po)

Electronegativity

Pauling scale2
Allred-Rochow scale1.76
Mulliken scale2.48
Nagle scale1.96

Other properties

Natural occurrenceDecay product
Crystal structureSimple cubic
Goldschmidt Classificationsynthetic
Superconductorwithout transition tempperature
Radioactivitysignificantly radioactive

Natural abundances

satellite_alt
sunny
destruction
water_drop
Oceans
2·10-11 ppb ≈ 27.3 g
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