39YYttrium

Yttrium is a chemical element with the symbol Y and atomic number 39. It is a silvery-metallic transition metal chemically similar to the lanthanides and has often been classified as a "rare-earth element". Yttrium is almost always found in combination with lanthanide elements in rare-earth minerals and is never found in nature as a free element. 89Y is the only stable isotope and the only isotope found in the Earth's crust.

The most important present-day use of yttrium is as a component of phosphors, especially those used in LEDs. Historically, it was once widely used in the red phosphors in television set cathode ray tube displays. Yttrium is also used in the production of electrodes, electrolytes, electronic filters, lasers, superconductors, various medical applications, and tracing various materials to enhance their properties.

Yttrium has no known biological role. Exposure to yttrium compounds can cause lung disease in humans. The element is named after ytterbite, a mineral first identified in 1787 by the chemist Carl Axel Arrhenius. He named the mineral after the village of Ytterby, in Sweden, where it had been discovered. When one of the chemicals in ytterbite was later found to be a previously unidentified element, the element was then named yttrium after the mineral.

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Atomic properties

Standard atomic weight88.9058 ±2·10-6
Atomic mass88.9058 u

Atomic radii

Radius (empirical)180 pm
Radius (calculated)212 pm
Covalent radius190 ±7 pm

Atomic shell

Electron configurationKr 4d1 5s2
Ionization energy(1st) 6.21726 eV
(2nd) 12.2236 eV
(3rd) 20.52441 eV
(4th) 60.6072 eV
(5th) 75.35 eV
Shell model
Electrons
k-shell:2
l-shell:8
m-shell:18
n-shell:9
o-shell:2

Physical properties

Phasesolid
Density4.472 g·cm−3
Molar volume1.988·10-5 m3·mol−1
Speed of sound3,300 m·s−1 (293.1 K)

Temperatures

Melting point1,799 K
Boiling point3,203 K
Liquid range1,404 K
Transition temperature2.8 K

Enthalpies

Melting enthalpy11.4 kJ·mol-1
Enthalpy of vaporization380 kJ·mol-1
Binding energy425 kJ·mol-1

Heat and conductivity

Thermal conductivity17 W·m-1·K-1
Expansion coefficient1.06·10-5 K-1

Hardnesses

Brinell hardness589 NM·m-2

Elastic properties

Young’s modulus64 GPa
Shear modulus26 GPa
Bulk modulus41 GPa
Poisson’s ratio0.24

Electrical properties

Electrical conductivity1.66·106 S·m-1
Resistance6·10-7 Ωm

Magnetism

Magnetismparamagnetic
Magnetic susceptibility2.15·10-6 cm3·mol−1 (298 K)

Chemical properties

Basicityslightly basic
Oxidation state+3
Standard potential-2.37 V (Y3+ + 3e- → Y)

Electronegativity

Pauling scale1.22
Sanderson scale0.65
Allred-Rochow scale1.11
Ghosh-Gupta scale2.723 eV
Nagle scale1.11
Pearson absolute negativity3.19 eV

Other properties

Natural occurrenceprimordial
Crystal structureHexagonal close-packed
Goldschmidt Classificationlithophile
Superconductorwith transition tempperature under special conditions
Price/kg31 USD

Natural abundances

satellite_alt
Universe
7 ppb ≈ 7.03·1010 M☉
sunny
Sun
10 ppb ≈ 1.98·1010 Mt
destruction
Meteorite
1,900 ppb ≈ 1.9 g
public
Earth’s crust
29,000 ppb ≈ 803,000 Mt
water_drop
Oceans
0.013 ppb ≈ 17.8 kt
waves
Flowing water
50 ppb ≈ 800 kt
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