66DyDysprosium

Dysprosium is the chemical element with the symbol Dy and atomic number 66. It is a rare-earth element in the lanthanide series with a metallic silver luster. Dysprosium is never found in nature as a free element, though, like other lanthanides, it is found in various minerals, such as xenotime. Naturally occurring dysprosium is composed of seven isotopes, the most abundant of which is 164Dy.

Dysprosium was first identified in 1886 by Paul Émile Lecoq de Boisbaudran, but it was not isolated in pure form until the development of ion-exchange techniques in the 1950s. Dysprosium has relatively few applications where it cannot be replaced by other chemical elements. It is used for its high thermal neutron absorption cross-section in making control rods in nuclear reactors, for its high magnetic susceptibility (χv ≈ 5. 44×10−3) in data-storage applications, and as a component of Terfenol-D (a magnetostrictive material). Soluble dysprosium salts are mildly toxic, while the insoluble salts are considered non-toxic.

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Atomic properties

Standard atomic weight162.5 ±0.001
Atomic mass162.5 u

Atomic radii

Radius (empirical)178 pm
Radius (calculated)228 pm
Covalent radius192 ±7 pm

Atomic shell

Electron configurationXe 4f10 6s2
Ionization energy(1st) 5.93905 eV
(2nd) 11.647 eV
(3rd) 22.89 eV
(4th) 41.23 eV
(5th) 62.1 eV
Shell model
Electrons
k-shell:2
l-shell:8
m-shell:18
n-shell:28
o-shell:8
p-shell:2

Physical properties

Phasesolid
Density8.559 g·cm−3 (298.1 K)
Molar volume1.901·10-5 m3·mol−1
Speed of sound2,710 m·s−1 (293.1 K)

Temperatures

Melting point1,680 K
Boiling point2,840 K
Liquid range1,160 K

Enthalpies

Melting enthalpy11.1 kJ·mol-1
Enthalpy of vaporization280 kJ·mol-1
Binding energy290 kJ·mol-1

Heat and conductivity

Thermal conductivity11 W·m-1·K-1
Expansion coefficient9.9·10-6 K-1

Hardnesses

Brinell hardness500 NM·m-2
Vickers hardness540 NM·m-2

Elastic properties

Young’s modulus61 GPa
Shear modulus25 GPa
Bulk modulus41 GPa
Poisson’s ratio0.25

Electrical properties

Electrical conductivity1.08·106 S·m-1
Resistance9.26·10-7 Ωm

Magnetism

Magnetismparamagnetic
Magnetic susceptibility0.104 cm3·mol−1 (293.2 K)

Chemical properties

Basicityslightly basic
Oxidation state3
Standard potential-2.29 V (Dy3+ + 3e- → Dy)

Electronegativity

Pauling scale1.22
Allred-Rochow scale1.1
Nagle scale1.09

Other properties

Natural occurrenceprimordial
Crystal structureHexagonal close-packed
Goldschmidt Classificationlithophile
Superconductorwithout transition tempperature
Price/kg307 USD

Natural abundances

satellite_alt
Universe
2 ppb ≈ 2.01·1010 M☉
sunny
Sun
2 ppb ≈ 3.97·109 Mt
destruction
Meteorite
280 ppb ≈ 280 mg
public
Earth’s crust
6,200 ppb ≈ 171,000 Mt
water_drop
Oceans
9.1·10-4 ppb ≈ 1.24 kt
waves
Flowing water
0.05 ppb ≈ 800 t
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