49InIndium

Indium is a chemical element; it has symbol In and atomic number 49. It is a silvery-white post-transition metal and one of the softest elements. Chemically, indium is similar to gallium and thallium, and its properties are largely intermediate between the two. It was discovered in 1863 by Ferdinand Reich and Hieronymous Theodor Richter by spectroscopic methods and named for the indigo blue line in its spectrum.

Indium is used primarily in the production of flat-panel displays as indium tin oxide (ITO), a transparent and conductive coating applied to glass. It is also used in the semiconductor industry, in low-melting-point metal alloys such as solders and soft-metal high-vacuum seals. It is used in the manufacture of blue and white LED circuits, mainly to produce Indium gallium nitride p-type semiconductor substrates. It is produced exclusively as a by-product during the processing of the ores of other metals, chiefly from sphalerite and other zinc sulfide ores.

Indium has no biological role and its compounds are toxic when inhaled or injected into the bloodstream, although they are poorly absorbed following ingestion.

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Atomic properties

Standard atomic weight114.818 ±0.001
Atomic mass114.818 u

Atomic radii

Radius (empirical)167 pm
Radius (calculated)156 pm
Covalent radius142 ±5 pm
Van der Waals radius193 pm

Atomic shell

Electron configurationKr 4d10 5s2 5p1
Ionization energy(1st) 5.7863556 eV
(2nd) 18.87041 eV
(3rd) 28.04415 eV
(4th) 55.45 eV
(5th) 69.3 eV
Shell model
Electrons
k-shell:2
l-shell:8
m-shell:18
n-shell:18
o-shell:3

Physical properties

Phasesolid
Density7.31 g·cm−3
Molar volume1.576·10-5 m3·mol−1
Speed of sound1,215 m·s−1 (293.1 K)

Temperatures

Melting point429.7 K
Boiling point2,345 K
Liquid range1,915 K
Triple point429.7 K @ 1 kPa
Transition temperature3.4 K

Enthalpies

Melting enthalpy3.26 kJ·mol-1
Enthalpy of vaporization230 kJ·mol-1
Binding energy243 kJ·mol-1

Heat and conductivity

Specific heat capacity233 J·kg−1·K−1
Thermal conductivity81.6 W·m-1·K-1
Expansion coefficient3.21·10-5 K-1

Hardnesses

Mohs hardness1.2
Brinell hardness8.83 NM·m-2

Elastic properties

Young’s modulus11 GPa

Electrical properties

Electrical conductivity1.25·107 S·m-1
Resistance8·10-8 Ωm

Magnetism

Magnetismdiamagnetic
Magnetic susceptibility-6.4·10-5 cm3·mol−1 (298 K)

Chemical properties

Basicityamphoteric
Oxidation state3, 1
Standard potential-0.343 V (In3+ + 3e- → In)

Electronegativity

Pauling scale1.78
Sanderson scale2.14
Allred-Rochow scale1.49
Mulliken scale1.76
Allen scale1.656
Ghosh-Gupta scale4.253 eV
Nagle scale1.52
Pearson absolute negativity3.1 eV

Other properties

Natural occurrenceprimordial
Crystal structureTetragonal
Goldschmidt Classificationchalcophile
Superconductorwith transition temperature (solid body, normal pressure)
Price/kg167 USD

Natural abundances

satellite_alt
Universe
0.3 ppb ≈ 3.01·109 M☉
sunny
Sun
4 ppb ≈ 7.95·109 Mt
destruction
Meteorite
45 ppb ≈ 45 mg
public
Earth’s crust
160 ppb ≈ 4,430 Mt
water_drop
Oceans
1·10-4 ppb ≈ 137 t
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