49InIndium

Indium is a chemical element with the symbol In and atomic number 49. Indium is the softest metal that is not an alkali metal. It is a silvery-white metal that resembles tin in appearance. It is a post-transition metal that makes up 0. 21 parts per million of the Earth's crust. Indium has a melting point higher than sodium and gallium, but lower than lithium and tin. Chemically, indium is similar to gallium and thallium, and it is largely intermediate between the two in terms of its properties. Indium was discovered in 1863 by Ferdinand Reich and Hieronymous Theodor Richter by spectroscopic methods. They named it for the indigo blue line in its spectrum. Indium was isolated the next year.

Indium is a minor component in zinc sulfide ores and is produced as a byproduct of zinc refinement. It is most notably used in the semiconductor industry, in low-melting-point metal alloys such as solders, in soft-metal high-vacuum seals, and in the production of transparent conductive coatings of indium tin oxide (ITO) on glass. Indium is considered a technology-critical element.

Indium has no biological role. Its compounds are toxic when injected into the bloodstream. Most occupational exposure is through ingestion, from which indium compounds are not absorbed well, and inhalation, from which they are moderately absorbed.

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Atomic properties

Standard atomic weight114.818 ±0.001
Atomic mass114.818 u

Atomic radii

Radius (empirical)167 pm
Radius (calculated)156 pm
Covalent radius142 ±5 pm
Van der Waals radius193 pm

Atomic shell

Electron configurationKr 4d10 5s2 5p1
Ionization energy(1st) 5.7863556 eV
(2nd) 18.87041 eV
(3rd) 28.04415 eV
(4th) 55.45 eV
(5th) 69.3 eV
Shell model
Electrons
k-shell:2
l-shell:8
m-shell:18
n-shell:18
o-shell:3

Physical properties

Phasesolid
Density7.31 g·cm−3
Molar volume1.576·10-5 m3·mol−1
Speed of sound1,215 m·s−1 (293.1 K)

Temperatures

Melting point429.7 K
Boiling point2,345 K
Liquid range1,915 K
Triple point429.7 K @ 1 kPa
Transition temperature3.4 K

Enthalpies

Melting enthalpy3.26 kJ·mol-1
Enthalpy of vaporization230 kJ·mol-1
Binding energy243 kJ·mol-1

Heat and conductivity

Specific heat capacity233 J·kg−1·K−1
Thermal conductivity81.6 W·m-1·K-1
Expansion coefficient3.21·10-5 K-1

Hardnesses

Mohs hardness1.2
Brinell hardness8.83 NM·m-2

Elastic properties

Young’s modulus11 GPa

Electrical properties

Electrical conductivity1.25·107 S·m-1
Resistance8·10-8 Ωm

Magnetism

Magnetismdiamagnetic
Magnetic susceptibility-6.4·10-5 cm3·mol−1 (298 K)

Chemical properties

Basicityamphoteric
Oxidation state3, 1
Standard potential-0.343 V (In3+ + 3e- → In)

Electronegativity

Pauling scale1.78
Sanderson scale2.14
Allred-Rochow scale1.49
Mulliken scale1.76
Allen scale1.656
Ghosh-Gupta scale4.253 eV
Nagle scale1.52
Pearson absolute negativity3.1 eV

Other properties

Natural occurrenceprimordial
Crystal structureTetragonal
Goldschmidt Classificationchalcophile
Superconductorwith transition tempperature (solid body, normal pressure)
Price/kg167 USD

Natural abundances

satellite_alt
Universe
0.3 ppb ≈ 3.01·109 M☉
sunny
Sun
4 ppb ≈ 7.95·109 Mt
destruction
Meteorite
45 ppb ≈ 45 mg
public
Earth’s crust
160 ppb ≈ 4,430 Mt
water_drop
Oceans
1·10-4 ppb ≈ 137 t
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