68ErErbium

Erbium is a chemical element with the symbol Er and atomic number 68. A silvery-white solid metal when artificially isolated, natural erbium is always found in chemical combination with other elements. It is a lanthanide, a rare-earth element, originally found in the gadolinite mine in Ytterby, Sweden, which is the source of the element's name.

Erbium's principal uses involve its pink-colored Er3+ ions, which have optical fluorescent properties particularly useful in certain laser applications. Erbium-doped glasses or crystals can be used as optical amplification media, where Er3+ ions are optically pumped at around 980 or 1480 nm and then radiate light at 1530 nm in stimulated emission. This process results in an unusually mechanically simple laser optical amplifier for signals transmitted by fiber optics. The 1550 nm wavelength is especially important for optical communications because standard single mode optical fibers have minimal loss at this particular wavelength.

In addition to optical fiber amplifier-lasers, a large variety of medical applications (i. e. dermatology, dentistry) rely on the erbium ion's 2940 nm emission (see Er:YAG laser) when lit at another wavelength, which is highly absorbed in water in tissues, making its effect very superficial. Such shallow tissue deposition of laser energy is helpful in laser surgery, and for the efficient production of steam which produces enamel ablation by common types of dental laser.

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Atomic properties

Standard atomic weight167.259 ±0.003
Atomic mass167.259 u

Atomic radii

Radius (empirical)176 pm
Radius (calculated)226 pm
Covalent radius189 ±6 pm

Atomic shell

Electron configurationXe 4f12 6s2
Ionization energy(1st) 6.1077 eV
(2nd) 11.916 eV
(3rd) 22.7 eV
(4th) 42.42 eV
(5th) 65.1 eV
Shell model
Electrons
k-shell:2
l-shell:8
m-shell:18
n-shell:30
o-shell:8
p-shell:2

Physical properties

Phasesolid
Density9.045 g·cm−3 (298.1 K)
Molar volume1.846·10-5 m3·mol−1
Speed of sound2,830 m·s−1

Temperatures

Melting point1,802 K
Boiling point3,141 K
Liquid range1,339 K

Enthalpies

Melting enthalpy19.9 kJ·mol-1
Enthalpy of vaporization285 kJ·mol-1
Binding energy317 kJ·mol-1

Heat and conductivity

Thermal conductivity15 W·m-1·K-1
Expansion coefficient1.22·10-5 K-1

Hardnesses

Brinell hardness814 NM·m-2
Vickers hardness589 NM·m-2

Elastic properties

Young’s modulus70 GPa
Shear modulus28 GPa
Bulk modulus44 GPa
Poisson’s ratio0.24

Electrical properties

Electrical conductivity1.16·106 S·m-1
Resistance8.6·10-7 Ωm

Magnetism

Magnetismparamagnetic
Magnetic susceptibility0.0443 cm3·mol−1

Chemical properties

Basicitybasic
Oxidation state3
Standard potential-2.32 V (Er3+ + 3e- → Er)

Electronegativity

Pauling scale1.24
Allred-Rochow scale1.11
Nagle scale1.11

Other properties

Natural occurrenceprimordial
Crystal structureHexagonal close-packed
Goldschmidt Classificationlithophile
Superconductorwithout transition tempperature
Price/kg26.4 USD

Natural abundances

satellite_alt
Universe
2 ppb ≈ 2.01·1010 M☉
sunny
Sun
1 ppb ≈ 1.98·109 Mt
destruction
Meteorite
180 ppb ≈ 180 mg
public
Earth’s crust
3,000 ppb ≈ 83,100 Mt
water_drop
Oceans
9·10-4 ppb ≈ 1.23 kt
waves
Flowing water
0.05 ppb ≈ 800 t
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