8OOxygen

Oxygen is a chemical element; it has the symbol O and its atomic number is 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and a potent oxidizing agent that readily forms oxides with most elements as well as with other compounds. Oxygen is the most abundant element in Earth's crust, making up almost half of the Earth's crust in the form of various oxides such as water, carbon dioxide, iron oxides and silicates. It is the third-most abundant element in the universe after hydrogen and helium.

At standard temperature and pressure, two oxygen atoms will bind covalently to form dioxygen, a colorless and odorless diatomic gas with the chemical formula O2. Dioxygen gas currently constitutes approximately 20. 95% molar fraction of the Earth's atmosphere, though this has changed considerably over long periods of time in Earth's history. A much rarer triatomic allotrope of oxygen, ozone (O3), strongly absorbs the UVB and UVC wavelengths and forms a protective ozone layer at the lower stratosphere, which shields the biosphere from ionizing ultraviolet radiation. However, ozone present at the surface is a corrosive byproduct of smog and thus an air pollutant.

All eukaryotic organisms, including plants, animals, fungi, algae and most protists, need oxygen for cellular respiration, a process that extracts chemical energy by the reaction of oxygen with organic molecules derived from food and releases carbon dioxide as a waste product.

Many major classes of organic molecules in living organisms contain oxygen atoms, such as proteins, nucleic acids, carbohydrates and fats, as do the major constituent inorganic compounds of animal shells, teeth, and bone. Most of the mass of living organisms is oxygen as a component of water, the major constituent of lifeforms. Oxygen in Earth's atmosphere is produced by biotic photosynthesis, in which photon energy in sunlight is captured by chlorophyll to split water molecules and then react with carbon dioxide to produce carbohydrates and oxygen is released as a byproduct. Oxygen is too chemically reactive to remain a free element in air without being continuously replenished by the photosynthetic activities of autotroph such as cyanobacteria, chloroplast-bearing algae and plants.

Oxygen was isolated by Michael Sendivogius before 1604, but it is commonly believed that the element was discovered independently by Carl Wilhelm Scheele, in Uppsala, in 1773 or earlier, and Joseph Priestley in Wiltshire, in 1774. Priority is often given for Priestley because his work was published first. Priestley, however, called oxygen "dephlogisticated air", and did not recognize it as a chemical element. In 1777, Antoine Lavoisier first recognized oxygen as a chemical element and correctly characterized the role it plays in combustion.

Common industrial uses of oxygen include production of steel, plastics and textiles, brazing, welding and cutting of steels and other metals, rocket propellant, oxygen therapy, and life-support systems in aircraft, submarines, spaceflight and diving.

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Atomic properties

Standard atomic weight15.999 ±0.001 [15.999 … 15.9997]
Atomic mass15.9991 u

Atomic radii

Radius (empirical)60 pm
Radius (calculated)48 pm
Covalent radius66 ±2 pm
Van der Waals radius152 pm

Atomic shell

Electron configurationHe 2s2 2p4
Ionization energy(1st) 13.618055 eV
(2nd) 35.12112 eV
(3rd) 54.93554 eV
(4th) 77.4135 eV
(5th) 113.899 eV
(6th) 138.1189 eV
Shell model
Electrons
k-shell:2
l-shell:6

Physical properties

Phasegaseous
Density0.001429 g·cm−3 (273.1 K)
Molar volume1.736·10-5 m3·mol−1
Speed of sound317.5 m·s−1 (293 K)

Temperatures

Melting point54.36 K
Boiling point90.18 K
Liquid range35.82 K
Triple point54.36 K @ 0.1463 kPa
Critical point154.5 K @ 5.043 MPa
Transition temperature0.6 K

Enthalpies

Melting enthalpy0.222 kJ·mol-1
Enthalpy of vaporization3.41 kJ·mol-1
Binding energy249 kJ·mol-1

Heat and conductivity

Specific heat capacity920 J·kg−1·K−1 (298 K)
Thermal conductivity0.02658 W·m-1·K-1

Magnetism

Magnetismparamagnetic
Magnetic susceptibility0.00345 cm3·mol−1 (293 K)

Optical properties

Refractive indexgaseous: 1
liquid: 1.221

Chemical properties

Basicity-
Oxidation state-2, -1, 0, +1, +2
Standard potential1.23 V

Electronegativity

Pauling scale3.44
Sanderson scale3.65
Allred-Rochow scale3.5
Mulliken scale3.41
Allen scale3.61
Ghosh-Gupta scale8.786 eV
Boyd-Edgecombe scale3.62
Nagle scale3.62
Pearson absolute negativity7.54 eV

Other properties

Natural occurrenceprimordial
Crystal structureSimple cubic
Goldschmidt Classificationlithophile
Superconductorwith transition temperature (solid body, normal pressure)
Price/kg0.154 USD

Natural abundances

satellite_alt
Universe
1·107 ppb ≈ 1·1017 M☉
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Sun
9·106 ppb ≈ 1.79·1016 Mt
destruction
Meteorite
4.1·108 ppb ≈ 410 kg
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Earth’s crust
4.6·108 ppb ≈ 1.27·1010 Mt
water_drop
Oceans
8.57·108 ppb ≈ 1.17·106 Mt
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Flowing water
8.8·108 ppb ≈ 14,000 Mt
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Human body
6.1·108 ppb ≈ 42.6 kg