96CmCurium

Curium is a transuranic, radioactive chemical element with the symbol Cm and atomic number 96. This actinide element was named after eminent scientists Marie and Pierre Curie, both known for their research on radioactivity. Curium was first intentionally made by the team of Glenn T. Seaborg, Ralph A. James, and Albert Ghiorso in 1944, using the cyclotron at Berkeley. They bombarded the newly discovered element plutonium (the isotope 239Pu) with alpha particles. This was then sent to the Metallurgical Laboratory at University of Chicago where a tiny sample of curium was eventually separated and identified. The discovery was kept secret until after the end of World War II. The news was released to the public in November 1947. Most curium is produced by bombarding uranium or plutonium with neutrons in nuclear reactors – one tonne of spent nuclear fuel contains ~20 grams of curium.

Curium is a hard, dense, silvery metal with a high melting and boiling point for an actinide. It is paramagnetic at ambient conditions, but becomes antiferromagnetic upon cooling, and other magnetic transitions are also seen in many curium compounds. In compounds, curium usually has valence +3 and sometimes +4; the +3 valence is predominant in solutions. Curium readily oxidizes, and its oxides are a dominant form of this element. It forms strongly fluorescent complexes with various organic compounds, but there is no evidence of its incorporation into bacteria and archaea. If it gets into the human body, curium accumulates in bones, lungs, and liver, where it promotes cancer.

All known isotopes of curium are radioactive and have small critical mass for a nuclear chain reaction. They mostly emit α-particles; radioisotope thermoelectric generators can use the heat from this process, but this is hindered by the rarity and high cost of curium. Curium is used in making heavier actinides and the 238Pu radionuclide for power sources in artificial cardiac pacemakers and RTGs for spacecraft. It served as the α-source in the alpha particle X-ray spectrometers of several space probes, including the Sojourner, Spirit, Opportunity, and Curiosity Mars rovers and the Philae lander on comet 67P/Churyumov–Gerasimenko, to analyze the composition and structure of the surface.

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Atomic properties

Atomic mass(247.07 u)

Atomic radii

Radius (empirical)174 pm
Covalent radius169 ±3 pm

Atomic shell

Electron configurationRn 5f7 6d1 7s2
Ionization energy(1st) 5.99141 eV
(2nd) 12.4 eV
(3rd) 20.1 eV
(4th) 37.7 eV
(5th) 51 eV
Shell model
Electrons
k-shell:2
l-shell:8
m-shell:18
n-shell:32
o-shell:25
p-shell:9
q-shell:2

Physical properties

Phasesolid
Density13.51 g·cm−3
Molar volume1.805·10-5 m3·mol−1

Temperatures

Melting point1,613 K
Boiling point3,383 K
Liquid range1,770 K

Enthalpies

Enthalpy of vaporization(320 kJ·mol-1)

Heat and conductivity

Thermal conductivity10 W·m-1·K-1 (300 K)

Magnetism

Magnetismantiferromagnetic

Chemical properties

Basicity-
Oxidation state(+2), +3, +4
Standard potential-2.06 V (Cm3+ + 3e- → Cm)

Electronegativity

Pauling scale1.3
Allred-Rochow scale1.2
Nagle scale1.11

Other properties

Natural occurrencesynthetic
Crystal structureDouble hexagonal close-packed
Goldschmidt Classificationsynthetic
Superconductorwithout transition tempperature
Radioactivityslightly radioactive