37RbRubidium

Rubidium is the chemical element with the symbol Rb and atomic number 37. It is a very soft, whitish-grey solid in the alkali metal group, similar to potassium and caesium. Rubidium is the first alkali metal in the group to have a density higher than water. On Earth, natural rubidium comprises two isotopes: 72% is a stable isotope 85Rb, and 28% is slightly radioactive 87Rb, with a half-life of 48. 8 billion years—more than three times as long as the estimated age of the universe.

German chemists Robert Bunsen and Gustav Kirchhoff discovered rubidium in 1861 by the newly developed technique, flame spectroscopy. The name comes from the Latin word rubidus, meaning deep red, the color of its emission spectrum. Rubidium's compounds have various chemical and electronic applications. Rubidium metal is easily vaporized and has a convenient spectral absorption range, making it a frequent target for laser manipulation of atoms. Rubidium is not a known nutrient for any living organisms. However, rubidium ions have similar properties and the same charge as potassium ions, and are actively taken up and treated by animal cells in similar ways.

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Atomic properties

Standard atomic weight85.4678 ±3·10-4
Atomic mass85.4678 u

Atomic radii

Radius (empirical)248 pm
Radius (calculated)265 pm
Covalent radius220 ±9 pm
Van der Waals radius303 pm

Atomic shell

Electron configurationKr 5s1
Ionization energy(1st) 4.177128 eV
(2nd) 27.28954 eV
(3rd) 39.247 eV
(4th) 52.2 eV
(5th) 68.44 eV
Shell model
Electrons
k-shell:2
l-shell:8
m-shell:18
n-shell:8
o-shell:1

Physical properties

Phasesolid
Density1.532 g·cm−3 (293.1 K)
Molar volume5.576·10-5 m3·mol−1
Speed of sound1,300 m·s−1 (293.1 K)

Temperatures

Melting point312.4 K
Boiling point961 K
Liquid range648.5 K
Triple point(312.4 K)
Critical point(2,093 K @ 16 MPa)

Enthalpies

Melting enthalpy2.19 kJ·mol-1
Enthalpy of vaporization72 kJ·mol-1
Binding energy81 kJ·mol-1

Heat and conductivity

Thermal conductivity58 W·m-1·K-1
Work function2.16 eV

Hardnesses

Mohs hardness0.3
Brinell hardness0.216 NM·m-2

Elastic properties

Young’s modulus2.4 GPa
Bulk modulus2.5 GPa

Electrical properties

Electrical conductivity7.52·106 S·m-1
Resistance1.33·10-7 Ωm

Magnetism

Magnetismparamagnetic
Magnetic susceptibility1.7·10-5 cm3·mol−1 (303 K)

Chemical properties

Basicitystrongly basic
Oxidation state-1, +1
Standard potential-2.924 V (Rb+ + e- → Rb)

Electronegativity

Pauling scale0.82
Sanderson scale0.31
Allred-Rochow scale0.89
Mulliken scale0.69
Allen scale0.706
Ghosh-Gupta scale2.013 eV
Nagle scale0.83
Pearson absolute negativity2.34 eV

Other properties

Natural occurrenceprimordial
Crystal structureBody-centered cubic
Goldschmidt Classificationlithophile
Superconductorwithout transition tempperature
Price/kg15,500 USD

Natural abundances

satellite_alt
Universe
10 ppb ≈ 1·1011 M☉
sunny
Sun
30 ppb ≈ 5.96·1010 Mt
destruction
Meteorite
3,300 ppb ≈ 3.3 g
public
Earth’s crust
60,000 ppb ≈ 1.66·106 Mt
water_drop
Oceans
120 ppb ≈ 164 Gt
waves
Flowing water
1 ppb ≈ 16 kt
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Human body
4,600 ppb ≈ 322 mg