51SbAntimony

Antimony is a chemical element with the symbol Sb (from Latin stibium) and atomic number 51. A lustrous gray metalloid, it is found in nature mainly as the sulfide mineral stibnite (Sb2S3). Antimony compounds have been known since ancient times and were powdered for use as medicine and cosmetics, often known by the Arabic name kohl. The earliest known description of the metalloid in the West was written in 1540 by Vannoccio Biringuccio.

China is the largest producer of antimony and its compounds, with most production coming from the Xikuangshan Mine in Hunan. The industrial methods for refining antimony from stibnite are roasting followed by reduction with carbon, or direct reduction of stibnite with iron.

The largest applications for metallic antimony are in alloys with lead and tin, which have improved properties for solders, bullets, and plain bearings. It improves the rigidity of lead-alloy plates in lead–acid batteries. Antimony trioxide is a prominent additive for halogen-containing flame retardants. Antimony is used as a dopant in semiconductor devices.

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Atomic properties

Standard atomic weight121.76 ±0.001
Atomic mass121.76 u

Atomic radii

Radius (empirical)140 pm
Radius (calculated)133 pm
Covalent radius139 ±5 pm
Van der Waals radius206 pm

Atomic shell

Electron configurationKr 4d10 5s2 5p3
Ionization energy(1st) 8.608389 eV
(2nd) 16.626 eV
(3rd) 25.3235 eV
(4th) 43.804 eV
(5th) 55 eV
Shell model
Electrons
k-shell:2
l-shell:8
m-shell:18
n-shell:18
o-shell:5

Physical properties

Phasesolid
Density6.697 g·cm−3
Molar volume1.819·10-5 m3·mol−1
Speed of sound3,420 m·s−1

Temperatures

Melting point903.7 K
Boiling point1,908 K
Liquid range1,004 K
Transition temperature3.6 K

Enthalpies

Melting enthalpy19.7 kJ·mol-1
Enthalpy of vaporization68 kJ·mol-1
Binding energy262 kJ·mol-1

Heat and conductivity

Thermal conductivity24 W·m-1·K-1
Expansion coefficient1.1·10-5 K-1

Hardnesses

Mohs hardness3
Brinell hardness294 NM·m-2

Elastic properties

Young’s modulus55 GPa
Shear modulus20 GPa
Bulk modulus42 GPa

Electrical properties

Electrical conductivity2.5·106 S·m-1
Resistance4·10-7 Ωm

Magnetism

Magnetismdiamagnetic
Magnetic susceptibility-9.9·10-5 cm3·mol−1

Optical properties

Reflectivity55 %

Chemical properties

Basicityslightly acidic
Oxidation state-3, 3, 5
Standard potential0.15 V (Sb3+ + 3e- → Sb)

Electronegativity

Pauling scale2.05
Sanderson scale2.46
Allred-Rochow scale1.82
Mulliken scale2.12
Allen scale1.984
Ghosh-Gupta scale5.02 eV
Nagle scale1.88
Pearson absolute negativity4.85 eV

Other properties

Natural occurrenceprimordial
Crystal structureRhombohedral
Goldschmidt Classificationchalcophile
Superconductorwith transition tempperature under special conditions
Price/kg5.79 USD

Natural abundances

satellite_alt
Universe
0.4 ppb ≈ 4.02·109 M☉
sunny
Sun
1 ppb ≈ 1.98·109 Mt
destruction
Meteorite
120 ppb ≈ 120 mg
public
Earth’s crust
200 ppb ≈ 5,540 Mt
water_drop
Oceans
0.2 ppb ≈ 274 kt
waves
Flowing water
2 ppb ≈ 32 kt
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