Block
The classification of chemical elements as blocks is based on the most energetic orbitals of their electron shell. A block groups several groups of the periodic table together.
s-block
The s-subshell of the respective current main shell is filled. The block includes the 1st and 2nd group as well as the element helium. All s-elements except helium are highly reactive, metals of the s-block are strongly electropositive and have low melting and boiling points.
p-block
The p-block – p-subshells of the current main shell are filled – includes the 3rd to 8th main group (excluding helium). The reactivity of elements in a group generally decreases downwards.
d-block
Transition elements (excluding lanthanides and actinides) are grouped in the d-block. d-subshells hold 10 electrons each, all elements in this block are metals and they are referred to as “outer transition metals”.
f-block
Lanthanides and actinides (inner transition metals) are defined by the f-block. They have two valence electrons in the outermost main shell, their chemical differences are correspondingly small.